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  • 1
    Electronic Resource
    Electronic Resource
    Investigation of salt — Mixed solvent systems. XXXVII. Crystallization enthalpy of lithium chloride in mixed solvent systems (1990)
    Springer
    Journal of solution chemistry 19 (1990), S. 437-446 
    Details
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; lithium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpy of LiCl at 25°C in LiCl-H2O-cosolvent systems is determined calorimetrically as a function of the cosolvent content in the mixed solvent. This parameter is used for the investigation of heat phenomena accompanying the solvation of the salt in a saturated solution. The cosolvents employed include methanol, acetone, and N,N-dimethylformamide. The most pronounced change is effected by replacement of water with N,N-dimethylformamide.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00650376
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  • 2
    Electronic Resource
    Electronic Resource
    Investigations of salt — Mixed solvent systems XXXVIII. Crystallization enthalpy of magnesium chloride in mixed solvent systems (1990)
    Springer
    Journal of solution chemistry 19 (1990), S. 447-455 
    Details
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; magnesium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpies of MgCl2 in MgCl2−H2O-cosolvent systems at 25°C were determined calorimetrically as a function of the cosolvent content in the mixed solvent. Methanol, acetone, and N,N-dimethylformamide were employed as cosolvents. The results show the individual cosolvents to have very differently influences on the energy state of the salt in the saturated solution. The most pronounced changes are effected by an increase of the DMF content in the mixed solvent. The intensity of Mg2+-DMF interaction at a higher DMF content in the saturated solution considerably exceeds the Li+-DMF interaction in LiCl solutions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00650377
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    Paper (German National Licenses)
    Fulltext
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