ISSN:
0170-2041
Keywords:
Glycosphingolipids
;
Cerebrosides
;
Carbohydrates
;
Acanthacerebroside A
;
Acanthaster planci
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(R)-2-Hydroxytetracosanoic acid (2), prepared by using the chiral building block benzyl (R)-2,3-epoxypropyl ether (7), was coupled to (2S,3S,4R)-2-amino-1,3,4-hexadecanetriol (3) to give the ceramide 4. Glycosidation of 4 with D-glucopyranose affords acanthacerebroside A, (2S,3S,4R)-1-O-(β-D-glucopyranosyl)-2-[(R)-2-hydroxytetracosanoylamino]-1,3,4-hexadecanetriol (1).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1990199001192
Permalink