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  • 1
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    Lifetimes for OH and OD electronic states with resonance transitions in the region between 1700 and 1950 A (1975)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: The upper states of the OH and OD bands in the region between 1700 and 1950 A have been studied with a phase-shift radiative lifetime apparatus. Lifetimes varying from 1.8 to 2.9 ns have been found. Lifetimes for OH and OD are essentially the same, indicating that the upper states are likely to be depopulated via purely radiative processes under the present experimental conditions. Lifetimes have also been obtained for the C(2)Sigma(+) - A(2)Sigma(+) transition in OH and OD. These results are consistent with the preliminary analysis of Pryce (private communication) that the bands between 1700 and 1950 A in OH are partly due to the C(2)Sigma(+) - X(2)Pi sub i transition.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Journal of Chemical Physics; 63; Sept. 15
    Format: text
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  • 2
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    Interactions among the lower valence states of the OH radical (1974)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: In order to define the origins of experimentally observed predissociations within the A2 sigma/+/ state of OH, overlaps have been computed of the bound level vibrational wavefunctions in the A2 sigma/+/ state with the vibrational continua of states of OH arising from the ground electronic state separated atoms. The dependence of the transition moment upon internuclear distance is derived and compared with previous results. Implications of this analysis in terms of the two body formation of OH are indicated.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Journal of Chemical Physics; 61; Oct. 1
    Format: text
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