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  • 1
    Publication Date: 2011-08-19
    Description: An apparatus is described that will measure absolute absorption of millimeter radiation in gases. The method measures the change in the quality factor of a Fabry-Perot resonator with and without gas present. The magnitude of the change is interpreted in terms of the absorption of the lossy medium inside the resonator. Experiments have been performed on the 115-GHz CO line and the 119-GHz O2 line at two different temperatures to determine the linewidth parameter and the peak absorption value. These numbers can be combined to give the integrated intensity which can be accurately calculated from results of spectroscopy measurements. The CO results are within 2 percent percent of theoretically predicted valves. Measurements on O2 have shown that absorption can be measured as accurately as 0.5 dB/km with this technique. Results have been obtained for oxygen absolute absorption in the 60-80-GHz region.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: IEEE Transactions on Antennas and Propagation (ISSN 0018-926X); 36; 1136-114
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  • 2
    Publication Date: 2011-08-19
    Description: The dimerization products of the ClO + ClO reaction were investigated in a flowing chemical reactor using submillimeter wave spectroscopy. The major products were identified as the chlorine peroxide (Cl2O2) and chlorine dioxide (OClO). The rotational constants as well as a complete set of quartic centrifugal distortion constants were determined. The identification of the chlorine peroxide supports the earlier proposed ClO-dimer mechanisms, which partly explain the ozone hole formation during the Antarctic springtime.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Journal of Chemical Physics (ISSN 0021-9606); 91; 6588-659
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