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Near-infrared absorption spectra of (O-16)3 and (O-18)3 - Adiabatic energy of the 1A2 state? (1990)

Morton, J. ; Mauersberger, K. ; Anderson, S. M.

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Publication Date: 2011-08-19

Description: The band positions and isotope shifts for the weak vibronic bands of O3 near 1 micron are determined experimentally using a low-resolution dual-beam absorption spectrometer with a 0.2-m holographic-grating monochromator and identical absorption chambers of volume about 600 cu cm and optical path length 46 cm. The experimental setup and procedures and the signal-processing methods applied are described, and the results are presented in tables and graphs. It is found that the adiabatic energy of the 1A2 state lies 9990 + or - 70/cm (1.24 + or - 0.01 eV) above the electronic ground state, close to the O + O2 dissociation limit. The applicability of the present results to studies of O3 in the upper atmosphere is indicated.

Keywords: ATOMIC AND MOLECULAR PHYSICS

Type: Journal of Chemical Physics (ISSN 0021-9606); 93; 3826-383

Format: text

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