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  • ASTROPHYSICS  (3)
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  • 1
    Publication Date: 2011-08-19
    Description: The optical constants of four polycyclic aromatic hydrocarbon (PAH) molecules (benzene, pyrene, pentacene, and coronene) are determined from their measured laboratory absorption spectra. The Planck mean of the radiation pressure cross section is computed for each molecule and for amorphous carbon (AC) grains, and semiempirically estimated for large PAH molecules up to 400 carbon atoms. Assuming that PAHs are present in carbon-rich stellar outflows, the radiation pressure forces acting on them are calculated and compared with the radiation forces on AC particles. The results show that PAHs possess very different optical properties from AC grains. Small PAHs may experience an 'inverse greenhouse' effect in the inner part of the envelope, as they decouple from the gas close to the photosphere. The radiation pressure force on PAHs is always much less than the force at work on AC grains, and PAH molecules do not affect significantly the dynamics of the outflow.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 377; 541-552
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  • 2
    Publication Date: 2019-08-28
    Description: A detailed chemical kinetic scheme is applied to stellar envelope profiles of gas density and temperature profiles in order to study the formation of PAH molecules in carbon-rich stellar outflows. Chemical concentration profiles are calculated for several envelope models by integrating the coupled continuity equations that include spherically expanding flows from an inner boundary at the shock formation radius. The influence of the 'inverse greenhouse' effect experienced by small PAHs is investigated and shown to increase the PAH yield by many orders of magnitude. It is shown that the route through propargyl radicals could be an important channel to produce benzene. PAH formation yields are found to be extremely sensitive to gas density and temperature and are much smaller than values inferred from the observed dust content of late-type carbon-rich stellar envelopes. It is therefore unlikely that aromatic molecules are generated in the stellar outflow itself.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 401; 1; p. 269-287.
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  • 3
    Publication Date: 2019-08-27
    Description: The hypothesis that interstellar infrared emission originates from vibrationally excited polycyclic aromatic hydrocarbons (PAHs) requires that emission can arise from all vibrational levels that are energetically accessible. Due to anharmonicity, the emission from the upper vibrational levels is shifted to longer wavelengths from that of the v = 1-0 transition. It is shown that structure in the 3-micron region is readily and quantitatively explained by emission from upper vibrational levels of excited PAHs that contain a maximum of 20-30 carbon atoms. The asymmetrical broadening of the 11.3-micron emission band may also be due to anharmonicity.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 315; L61-L65
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