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  • 1
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    Ionized polycyclic aromatic hydrocarbons in space (1986)
    In:  CASI
    Details
    Publication Date: 2016-06-07
    Description: The mid-infrared spectrum of a continuously increasing number of stellar objects, planetary and reflection nebulae, H-II regions and extragalactic sources show a distinctive set of broad emission features at 3.3, 3.4, 6.2, 7.7, 8.6, and 11.3 micron known collectively as the unidentified infrared emission bands. A model is summarized in which the bands arise from positively charged polycyclic hydrocarbons (PAH's) on the basis of their low ionization potential and the excellent agreement between the emission bands and laboratory spectra of auto exhaust which contains these types of molecules. The proposed presence of PAHs in such a variety of objects points to their presence in the interstellar medium. Out of a previously published collection of solid state PAH radical cation spectra five were selected on the basis of the unique thermodynamic stability of their carrier and compared directly to the wavelengths of the DIB's. Although the match seems quite favorable, strongly suggesting that PAH radicals are the long sought after carrier of the diffuse interstellar absorption bands, much laboratory work must be done to test this hypothesis.
    Keywords: ASTROPHYSICS
    Type: NASA, Washington. Interrelationships among Circumstellar, Interstellar and Interplanetary Dust; 2 p
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  • 2
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    The hydrogen coverage of interstellar PAHs (1986)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: The rate at which the CH bond in interstellar Polycyclic Aromatic Hydrocarbons (PAHs) rupture due to the absorption of a UV photon has been calculated. The results show that small PAHs (less than or equal to 25 carbon atoms) are expected to be partially dehydrogenated in regions with intense UV fields, while large PAHs (greater than or equal to 25 atoms) are expected to be completely hydrogenated in those regions. Because estimate of the carbon content of interstellar PAHs lie in the range of 20 to 25 carbon atoms, dehydrogenation is probably not very important. Because of the absence of other emission features besides the 11.3 micrometer feature in ground-based 8 to 13 micrometer spectra, it has been suggested that interstellar PAHs are partially dehydrogenated. However, IRAS 8 to 22 micrometer spectra of most sources that show strong 7.7 and 11.2 micrometer emission features also show a plateau of emission extending from about 11.3 to 14 micrometer. Like the 11.3 micrometer feature, this new feature is attributed to the CH out of plane bending mode in PAHs. This new feature shows that interstellar PAHs are not as dehydrogenated as estimated from ground-based 8 to 13 micrometer spectra. It also constrains the molecular structure of interstellar PAHs. In particular, it seems that very condensed PAHs, such as coronene and circumcoronene, dominate the interstellar PAH mixture as expected from stability arguments.
    Keywords: ASTROPHYSICS
    Type: NASA-TM-89340 , NAS 1.15:89340 , DE87-003376 , CONF-8602110-2
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  • 3
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    Polycyclic aromatic hydrocarbon optical properties and contribution to the acceleration of stellar outflows (1991)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: The optical constants of four polycyclic aromatic hydrocarbon (PAH) molecules (benzene, pyrene, pentacene, and coronene) are determined from their measured laboratory absorption spectra. The Planck mean of the radiation pressure cross section is computed for each molecule and for amorphous carbon (AC) grains, and semiempirically estimated for large PAH molecules up to 400 carbon atoms. Assuming that PAHs are present in carbon-rich stellar outflows, the radiation pressure forces acting on them are calculated and compared with the radiation forces on AC particles. The results show that PAHs possess very different optical properties from AC grains. Small PAHs may experience an 'inverse greenhouse' effect in the inner part of the envelope, as they decouple from the gas close to the photosphere. The radiation pressure force on PAHs is always much less than the force at work on AC grains, and PAH molecules do not affect significantly the dynamics of the outflow.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 377; 541-552
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  • 4
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    The hydrogen coverage of interstellar PAHs (1987)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: The rate at which the CH bond in interstellar Polycyclic Aromatic Hydrocarbons (PAHs) rupture due to the absorption of a UV photon has been calculated. The results show that small PAHs (less than or equal to 25 carbon atoms) are expected to be partially dehydrogenated in regions with intense UV fields, while large PAHs (greater than or equal to 25 atoms) are expected to be completely hydrogenated in those regions. Because estimate of the carbon content of interstellar PAHs lie in the range of 20 to 25 carbon atoms, dehydrogenation is probably not very important. Because of the absence of other emission features besides the 11.3 micrometer feature in ground-based 8 to 13 micrometer spectra, it has been suggested that interstellar PAHs are partially dehydrogenated. However, IRAS 8 to 22 micrometer spectra of most sources that show strong 7.7 and 11.2 micrometer emission features also show a plateau of emission extending from about 11.3 to 14 micrometer. Like the 11.3 micrometer feature, this new feature is attributed to the CH out of plane bending mode in PAHs. This new feature shows that interstellar PAHs are not as dehydrogenated as estimated from ground-based 8 to 13 micrometer spectra. It also constrains the molecular structure of interstellar PAHs. In particular, it seems that very condensed PAHs, such as coronene and circumcoronene, dominate the interstellar PAH mixture as expected from stability arguments.
    Keywords: ASTROPHYSICS
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  • 5
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    Interstellar polycyclic aromatic hydrocarbons - The infrared emission bands, the excitation/emission mechanism, and the astrophysical implications (1989)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: A comprehensive study of the PAH hypothesis is presented, including the interstellar, IR spectral features which have been attributed to emission from highly vibrationally excited PAHs. Spectroscopic and IR emission features are discussed in detail. A method for calculating the IR fluorescence spectrum from a vibrationally excited molecule is described. Analysis of interstellar spectrum suggests that the PAHs which dominate the IR spectra contain between 20 and 40 C atoms. The results are compared with results from a thermal approximation. It is found that, for high levels of vibrational excitation and emission from low-frequency modes, the two methods produce similar results. Also, consideration is given to the relationship between PAH molecules and amorphous C particles, the most likely interstellar PAH molecular structures, the spectroscopic structure produced by PAHs and PAH-related materials in the UV portion of the interstellar extinction curve, and the influence of PAH charge on the UV, visible, and IR regions.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal Supplement Series (ISSN 0067-0049); 71; 733-775
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  • 6
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    The interaction of interstellar gas with stellar density wave packets (1974)
    In:  Other Sources
    Details
    Publication Date: 2011-08-16
    Description: We have numerically studied the interaction between interstellar gas and a gravitational perturbation produced by a fluctuation in the stellar mass distribution. For a simple equation of state, shock waves develop even if the gravitational perturbation is aperiodic and transient. In a medium which can change thermal phase, shocks do not form and the gas makes a transition directly to the cold, dense phase. The cold material has an anomalous velocity imparted to it by the gravitational perturbation and it becomes an accretion front moving through the hot gas and capturing it. The accretion fronts trigger thermal phase change on a large scale and can reproduce the extent of observed cold clouds. Furthermore their high mass is favorable to gravitational instability and subsequent star formation.
    Keywords: ASTROPHYSICS
    Type: Astronomy and Astrophysics; 36; 2, No; Nov. 197
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  • 7
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    Polycyclic aromatic hydrocarbons and the unidentified infrared emission bands - Auto exhaust along the Milky Way (1985)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: The unidentified infrared emission features (UIR bands) are attributed to a collection of partially hydrogenated, positively charged polycyclic aromatic hydrocarbons (PAHs). This assignment is based on a spectroscopic analysis of the UIR bands. Comparison of the observed interstellar 6.2 and 7.7-micron bands with the laboratory measured Raman spectrum of a collection of carbon-based particulates (auto exhaust) shows a very good agreement, supporting this identification. The infrared emission is due to relaxation from highly vibrationally and electronically excited states. The excitation is probably caused by UV photon absorption. The infrared fluorescence of one particular, highly vibrationally excited PAH (chrysene) is modeled. In this analysis the species is treated as a molecule rather than bulk material and the non-thermodynamic equilibrium nature of the emission is fully taken into account. From a comparison of the observed ratio of the 3.3 to 11.3-micron UIR bands with the model calculations, the average number of carbon atoms per molecule is estimated to be about 20. The abundance of interstellar PAHs is calculated to be about 2 x 10 to the -7th with respect to hydrogen.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 290; L25-L28
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  • 8
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    The IR emission features - Emission from PAH molecules and amorphous carbon particles (1987)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Given the current understanding of polycyclic aromatic hydrocarbons (PAHs), the spectroscopic data suggest that are at least two components which contribute to the interstellar emission spectrum: (1) free molecule-sized PAHs producing the narrow features and (2) amorphous carbon particles (which are primarily composed of an irregular 'lattice' of PAHs) contributing to the broad underlying components. An exact treatment of the IR fluorescence from highly vibrationally excited large molecules demonstrates that species containing between 20 and 30 carbon atoms are responsible for the narrow features, although the spectra match more closely with the spectra of amorphous carbon particles. It is concluded that, since little is known about the spectroscopic properties of free PAHs and PAH clusters, much laboratory work is required along with an observational program focusing on the spatial characteristics of the spectra.
    Keywords: ASTROPHYSICS
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  • 9
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    A study of the Mg II k line in Beta Persei (1981)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Spectral scans of the Mg II k line in Beta Per were obtained with Copernicus during two primary eclipses. A brief description of observation in a short frame mode is given. The observed data are compared with computed line profiles based on the eclipse geometry of spherical stars. It is shown that a nonuniform circumstellar envelope, or cloud, probably is present. In one scan, a red-shifted line of P Cygni-type profile appeared, indicating the occurrence of an unusual event in the close binary system.
    Keywords: ASTROPHYSICS
    Type: Astronomical Journal; 86; Feb. 198
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  • 10
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    Physical observations of comets: Their composition, origin and evolution (1991)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: The composition, origins, and evolution of comets were studied. The composition was studied using spectroscopic observations of primarily brighter comets at moderate and high resolution for the distribution of certain gases in the coma. The origins was addressed through an imaging search for the Kuiper belt of comets. The evolution was addressed by searching for a link between comets and asteroids using an imaging approach to search for an OH coma.
    Keywords: ASTROPHYSICS
    Type: NASA, Washington, Reports of Planetary Astronomy, 1991; p 29-31
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