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  • 85.30  (2)
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    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 49 (1989), S. 285-292 
    ISSN: 1432-0630
    Keywords: 73.40 ; 82.80 ; 85.30
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract UV(He I) and X-ray photoelectron spectroscopies (UPS and XPS) were used to examine the alloying behavior of AuGe ohmic contacts to silicon-doped 〈100〉 oriented n-type GaAs substrates. The reacted interface was then revealed by Ar ion sputter depth profiling at room temperature and after annealing in ultra high vacuum at 300°, 500°, or 700°C. The indiffusion of Au and the outdiffusion of Ga and As are evident. Instead of obtaining a maximum peak of the Ge profile on annealing in forming gas, we observed an increase of Ge indiffusion with temperature. The Au indiffusion results in a decrease in the Au 5d splitting and a shift of both levels to higher binding energy. Au-Ga alloy formation is indicated by the Au 4f levels, and is further supported by the observation of the metallic Ga peak. It has been concluded that the sample annealed at 500°C forms the Au-Ga alloy and the compound of As containing Ge more easily than the samples annealed at 300° or 700°C. This result is consistent with the observations of low contact resistance at the annealing temperature of ∼ 500°C for AuNiGe ohmic contacts to n-type GaAs.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 73.40 ; 82.80 ; 85.30
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract An ultra-thin AuGeNi alloy (84%/12%/4% by weight) overlayer of 5 nm was evaporated onto Te-doped n-type (100) oriented GaSb substrates. Samples were annealed in ultra-high vacuum (UHV), with a base pressure of 10−10 Torr at either 300°C, 500°C, or 700°C for 12 h. The reacted interface was then revealed by Ar ion sputter-depth profiling. The highest percentage of Ge in the deep interface region was observed for the sample annealed at 500°C. Annealing at 500°C also leads to a uniform distribution of Ga, Sb, and Au concentrations. Results show that virtually all Au, Ge, and Ni evaporate away after annealing at 700°C. Au-based AuGa alloy formation was indicated by the shifts of Au 4f core-levels and the metallic Ga 3d peak. The small variation of Au 4f core-levels with sputtering for samples annealed at 500°C is the evidence of AuGa uniform alloying from the surface to the interface. It has been, therefore, concluded that annealing at 500°C forms a more uniform distribution of cluster size throughout the interface than annealing at 300°C or 700°C.
    Type of Medium: Electronic Resource
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