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X-ray and vibrational studies of 8-aminoquinoline. Evidence for a three-center hydrogen bond (1997)

Van Meervelt, L. ; Goethals, M. ; Leroux, N. ; [et al.]

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 10 (1997), S. 680-686

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ISSN: 0894-3230

Keywords: 8-aminoquinoline ; x-ray structure ; vibrational spectra ; three-center hydrogen bond ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: -The x-ray structure of 8-aminoquinoline indicates that one of the NH bonds of the NH2 group forms a three-center hydrogen bond, the major component being the intramolecular hydrogen bond and the minor component the intermolecular hydrogen bond. The IR and Raman spectra of 8-aminoquinoline and of its N-deuterated counterpart reflect the non-equivalence of the two NH(D) bonds and the weakness of the hydrogen bridge. © 1997 John Wiley & Sons, Ltd.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

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