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  • 79.60.Cn  (1)
  • Empfindlichkeiten, Nachweisgrenzen, 10 mCi-Am(241)-Quelle  (1)
  • PACS. 32.80.Dz Autoionization - 78.40.Kc Metals, semimetals, and alloys - 78.70.Dm X-ray absorption spectra  (1)
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  • 1
    ISSN: 1432-0630
    Keywords: 75.50.Cc ; 78.20.Ls ; 79.60.Cn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract 4f Photoemission (PE) spectra from magnetically ordered rare-earth materials using circularly polarized X-rays exhibit strong Magnetic Circular Dichroism (MCD), i.e., the intensities of the individual multiplet lines depend on the relative orientation of sample magnetization and photon spin. On the example of the wellresolved Tb 4f PE multiplet, it is shown that in relevant cases 4f PE lines are essentially only observed for one magnetization direction, either parallel or antiparallel to the photon spin. These large MCD effects in 4f PE open new perspectives in the analysis of surface and thin-film magnetism and provide a sensor for the degree of circular polarization of soft X-rays over a wide photon-energy range. To demonstrate the potential of MCD in 4f PE as a magnetometer, we studied Gd(0001) and Tb(0001), where the magnetization of the topmost atomic (0001) layer can be easily separated from the bulk magnetization via the surface core-level shift. In multicomponent magnetic thin films containing different rare-earth elements 4f PE allows to monitor magnetization in an element-specilic way, e.g., in case of the hetero-magnetic interface 1 ML En/Gd(0001).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 12 (1999), S. 171-178 
    ISSN: 1434-6036
    Keywords: PACS. 32.80.Dz Autoionization - 78.40.Kc Metals, semimetals, and alloys - 78.70.Dm X-ray absorption spectra
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: Magnetic circular dichroism in lanthanide 4 f photoemission (PE) multiplets was studied across the 4 d-4 f excitation threshold for the example of Tb metal. The combined experimental and theoretical analysis demonstrates that resonant enhancement of the 4 f PE signal and large magnetic contrast in the PE intensity are obtained simultaneously, when the excitation energy is tuned to the absorption-edge maximum for parallel orientation of magnetization and circular-polarization light helicity.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 280 (1969), S. 109-114 
    ISSN: 1618-2650
    Keywords: Analyse von Wasser ; Röntgenfluorescenz-Spektrometrie ; Empfindlichkeiten, Nachweisgrenzen, 10 mCi-Am(241)-Quelle
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary Seven trace elements ranging from chromium to barium were preconcentrated on Amberlite IR-120 cation exchange paper and determined in an energy dispersive X-ray fluorescence system using a 10 mCi241Am source. Sensitivities were experimentally determined and checked with theoretically calculated values. The detection limits are compared with elemental levels present in typical surface waters and those allowed in drinking water. Appropriate conclusions as to feasibility of such a system for environmental monitoring are drawn.
    Notes: Abstract Sieben Spurenelemente im Bereich von Chrom bis Barium wurden auf Amberlite IR-120 Kationenaustauschpapier angereichert und durch energiedispersive Röntgenfluorescenzanalyse mit einer 10 mCi241Am-Quelle bestimmt. Die Übereinstimmung der experimentell gemessenen mit den theoretisch berechneten Empfindlichkeiten wird geprüft. Die Nachweisgrenzen werden verglichen mit den in typischen Oberflächengewässern vorkommenden und den in Trinkwasser maximal erlaubten Elementkonzentrationen. Die Möglichkeit der Anwendung in der Umweltanalytik wird diskutiert.
    Type of Medium: Electronic Resource
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