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  • 61.70 Y  (1)
  • Organic Chemistry  (1)
  • 1995-1999  (1)
  • 1960-1964  (1)
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  • 1
    ISSN: 1434-6036
    Keywords: 31.30 G ; 61.70 Y
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Using the111Cd-TDPAC (time differential perturbated angular correlation) method, the pressure dependence of the electric field gradient (EFG) in Sb and Sb1−x M x (M=ln, Zn, Ge, Pb, Cd, Sn) was investigated. The application of a phenomenological ansatz for the parametrisation of the pressure and temperature dependence of the EFG made it possible to combine temperature data gained in former studies [1], [2] with the pressure dependent data presented in this paper. The resulting pressure dependence of −2±0.2 MHz/kbar is shown to be independent of concentration and element of admixture. Results for the volume and explicit temperature dependence agree with existing information on the mixed system Sb1−x M x (M=ln, Zn, Ge, Pb, Cd, Sn); the investigation of the EFG in Sb1−x−y M x Pb y showed that the resulting EFG may be interpreted as the weighted sum of the individual contributions of the two metals.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 44 (1961), S. 1622-1645 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of phosphamidon, a new systemic insecticide, is describcd. By use of the 14C-labeled compound it is shown that in the bean plant phosphamidon undergoes rapid degradation, during which traces of the metabolites desethylphosphamidon,α-chloroacetoaceto-diethylamide, and α-chloroacetoaceto-ethylamide only are detectable. In order to explain the mechanism of the degradation reactions, the behaviour of phosphamidon towards acids and bases has been studied.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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