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  • 35.20.G  (1)
  • Springer  (1)
  • International Union of Crystallography (IUCr)
  • American Physical Society (APS)
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  • Springer  (1)
  • International Union of Crystallography (IUCr)
  • American Physical Society (APS)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 12 (1989), S. 533-536 
    ISSN: 1434-6079
    Keywords: 33.20.K ; 35.20.G ; 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The electronic (UV-visible) spectrum of the molecular cluster Au55(PPh3)12Cl6 shows features corresponding to the 520 nm plasma resonance and the shorter-wavelength interband transition of colloidal gold. These absorptions differ qualitatively from the simpler one-electron transitions of lower-nuclearity cluster molecules. Differential scanning calorimetry has been used to measure the enthalpy of decomposition of Au55(PPh3)12Cl6. The Au-Au bonding appears to be substantially stronger than in bulk gold.
    Type of Medium: Electronic Resource
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