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  • 33  (3)
  • 35  (3)
  • 82.50. − m  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 35 (1984), S. 1-5 
    ISSN: 1432-0649
    Keywords: 82.50 ; 33 ; 35
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Increase of the emission bandwidth of a high-pressure CO2 laser up to 1.5 cm−1 increases the multiphoton absorption cross-section of SF6. Comparison with the previously found [9] increased absorption for shorter pulses suggests that this is also a bandwidth effect. Spectral structures as narrow as 1 cm−1 above the 10th absorption step are invoked to explain the observations. The temperature effect, which disappears in the broad-band case, confirms this view.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0649
    Keywords: 82.50 ; 33 ; 35
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The dissociation probabilities of32SF6 and some of34SF6 have been measured at a large number of CO2 laser lines both at room temperature and at 140 K. The longwavelength wing of this dissociation spectrum is exponential in the wavenumber. Its logarithmic slope is proportional to the inverse temperature. Selectivities are high enough at 140 K, that the photons are consumed only for the rare isotope in the case of34SF6 and nearly so for36SF6. For33SF6 further improvement of the selectivity would be desirable.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 27 (1982), S. 191-194 
    ISSN: 1432-0649
    Keywords: 35 ; 36 ; 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Aqueous solutions of benzene were irradiated by focussed KrF laser light. The formation of phenol together with varying amounts of 1.3-cyclopentadiene-1-carboxaldehyde was shown by uv absorption measurements. A mechanism for this photo-oxidation via benzene radical cations produced by 2-photon ionization of benzene is proposed. Comparative gas phase laser experiments and experiments with unfocussed laser beams were consistent with previous results using incoherent light sources.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 15 (1978), S. 297-301 
    ISSN: 1432-0630
    Keywords: 33
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract In a double-resonance experiment, the absorption of various CO2 laser lines by sulfur hexafluoride was measured, before and after the SF6 was pumped by a fixed frequency CO2 laser to a level of 5 quanta/molecule. The absorption is substantially shifted to longer wavelengths. But the short wavelength wing of the absorption band is not completely bleached. Instead a shoulder of several cm−1 width is left. This shoulder is probably important for the explanation of the infrared laser induced dissociation of SF6.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 24 (1992), S. 47-56 
    ISSN: 1434-6079
    Keywords: 82.50. − m
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 13C isotope separation by multiphoton dissociation of CHClF2 was studied by a continuous-discharge CO2 laserQ-switched at 8 kHz. This laser can easily emit two or more wavelengths with good spatial and temporal overlap. The best irradiation results were obtained by the line pair 9P16 + 9P28. After optimizing also the pressures of CHClF2 and of buffer gases (He and Ar), the energy density and the gas speed, the process is now much less nonlinear than in previous experiments with a single wavelength. Differences to the TEA laser induced process were observed, and generally the pressure influence on yield and selectivity showed a variety of phenomena. They were interpreted in terms of collisional changes of spectra during the laser pulse.
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