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Calculations of energy levels for atoms with several valence electrons (1996)

Dzuba, V. A. ; Flambaum, V. V. ; Kozlov, M. G.

Springer

JETP letters 63 (1996), S. 882-887

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ISSN: 1090-6487

Keywords: 31.15.Ar ; 31.15.Md ; 31.25.Jf

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract A new ab initio method for doing high-accuracy calculations for atoms with more than one valence electron is described. An effective Hamiltonian for the valence electrons is formed using many body perturbation theory for the residual core-valence interaction. The configuration interaction method is used then to find the energy levels of the atom. Application to thallium shows that this method gives an accuracy of about 0.5% for the ionization potential and a few tenths of a percent for the first few energy intervals.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1134/1.567108

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