ISSN:
1572-9028
Keywords:
allyl iodide
;
3-iodopropene
;
allylpalladium chloride
;
selective oxidation catalyst
;
inelastic neutron scattering
;
vibrational spectra
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The inelastic neutron scattering spectra of allyl iodide (3-iodopropene, CH2=CHCH2I) and allylpalladium chloride, and allyl iodide dosed onto activated iron(III) oxide and iron antimonate catalysts at room temperature have been determined to characterise the adsorbed allyl species. The spectra are energy loss vibrational spectra in the range 16–4000 cm−1. Allyl iodide is not decomposed on the surface and interacts through the localised C = C bond, more strongly with iron antimonate than with iron(III) oxide.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1027242318399
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