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Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)] (2000)

Al-Jahdali, Mutlaq ; Baker, Paul K. ; Drew, Michael G.B.

Springer

Journal of chemical crystallography 30 (2000), S. 181-184

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ISSN: 1572-8854

Keywords: tungsten(II) ; diiodo ; dicarbonyl ; triisopropylphosphite ; 3-hexyne ; crystal structure

Source: Springer Online Journal Archives 1860-2000

Topics: Geosciences , Physics

Notes: Abstract [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)] crystallizes in the monoclinic space group P21/n, with a = 11.101(12), b = 16.272(18), c = 14.892(17) Å, β = 93.27(1), Z = 4. The geometry can be considered to be pseudo-octahedral, with the 3-hexyne ligand occupying one site, with two iodo-groups, and the P(OiPr)3 ligand completing the equational plane of ligands, with two trans-carbonyl groups occupying the axial sites.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1009531014474

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