ISSN:
1042-7147
Keywords:
3-heptanol
;
3-heptanone
;
oxygenation
;
magnesia-supported polytitanazane-platinum
;
inorganic polymer-metal complex
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
A kind of inorganic polymer-platinum complex, magnesia-supported polytitanazane-platinum complex (MgO-Ti-N-Pt), was prepared and used to catlayze the oxygenation of 3-heptanol. It was found that this kind of catalyst was very active and stable in the reaction. The objective product (3-heptanone) was obtained near 100% yield in 40 hr under moderate reaction temperature and atmospheric oxygen pressure.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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