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  • 550 - Earth sciences  (20)
  • single crystal structure  (9)
  • 25.70  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 328 (1987), S. 81-84 
    ISSN: 1434-601X
    Keywords: 25.70 ; 34.50.F
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We investigate the strength of angular correlations between coincident electron-positron pairs produced in Pb + Pb collisions at 5.7 MeV/u. The angular correlations are predicted to be observable at electron energies above 200 keV, almost independent of positron energy.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 324 (1986), S. 243-259 
    ISSN: 1434-601X
    Keywords: 13.90 ; 14.80 ; 25.70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Following up our earlier work and also stimulated by recent experimental results on positron production in heavy ion collisions we investigate various mechanisms for the production of a light, previously unknown particle in such collisions. As more conventional mechanisms seem to be inadequate we concentrate on processes directly or indirectly connected with the strong electric or magnetic fields and quark degrees of freedom in nuclei. We also consider modifications of the color confinement scheme. Our analysis is confined to schemes staying within the framework of the standardSU(3)c ×SU(2)×U(1) model. Since most of the possibilities discussed can be rejected, severe modifications of basic concepts of particle physics seem to be required if the production of a new particle is confirmed.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 1 (1986), S. 47-50 
    ISSN: 1434-6079
    Keywords: 34.50 ; 25.70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Molecular orbitalK x-rays emitted during Pb+Pb collisions are investigated. Two results are presented: A slight filling up of the minimum observed in the differential radiation cross-section is given by radiative transitions from theM-shell to theL-shell. The minima are shifted with increasing nuclear contact times to higher photon energies. The observation of the shift allows the estimation of the sticking time.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 8 (1988), S. 305-313 
    ISSN: 1434-6079
    Keywords: 25.70 ; 34.50.F
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In recent experiments at least two structures have been detected in positron spectra from subcritical (total chargeZ ≦ 174) heavy-ion collisions at bombarding energiesE Lab=5.7−5.9 MeV/n. The origin of these structures is unexplained up to now. Atomic effects have already been discussed as a possible source in a previous paper, where a schematic ansatz for the electronic transition matrix elements was employed. Meanwhile numerical calculations forK-vacancy formation also exhibited oscillations in the impact parameter dependence when using this ansatz. In this paper we report on a scaling law describing these oscillations. As a consequence certain subsidiary conditions have to be imposed on our schematic ansatz, which in turn yield a new understanding on eligible atomic sources for multiple structures in the emission spectra of positrons.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 387-391 
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Single Crystal Investigations on Fluoroperovskites MPdF3 (M = Rb, K) and PdF2Single crystal investigations on PdF2 (violet) confirm the tetragonale rutile structure [1, 2] with a = 495.44(3) pm, c = 338.48(3) pm, Z = 2, space group P42/mnm-D4h14 (No. 136) (xF = 0.3058(8)). RbPdF3 and KPdF3 have been obtained. RbPdF3 and KPdF3 both ruby-red single crystals crystallize cubic (perovskite-structure), space group Pm3m-Oh1 (No. 221) with a = 429.41(8) pm (RbPdF3) respectively a = 424.30(4) pm (KPdF3).
    Notes: Einkristalluntersuchungen an PdF2 (amethystfarben) bestätigen die Rutilstruktur [1, 2] mit a = 495,44(3) pm, c = 338,48(3) pm, Z = 2, Raumgruppe P42/mnm-D4h14 (Nr. 136) (xF = 0,3058(8)). RbPdF3 und KPdF3 (beides rubinrote Einkristalle) kristallisieren in der kubischen Perowskitstruktur, Raumgruppe Pm3m-Oh1 (Nr. 221) mit a = 429,41(8) pm (RbPdF3) bzw. a = 424,30(4) pm (KPdF3).
    Additional Material: 8 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1223-1226 
    ISSN: 0044-2313
    Keywords: Fluorotitanates(IV) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: CsTi8F33 - the Last Step on the Way to TiF4CsTi8F33 has been prepared for the first time as a byproduct of the synthesis of TiF4. The colourless compound crystallizes trigonal in the spacegroup P31c-C3v4 (No. 159) with a = 862 pm, c = 1 902 pm and Z = 2.
    Notes: CsTi8F33 wurde erstmals in Form farbloser, transparenter Einkristalle als Nebenprodukt bei Versuchen zur Darstellung von TiF4-Einkristallen [1] erhalten. Es kristallisiert trigonal in der nicht zentrosymmetrischen Raumgruppe P31c-C3v4 (Nr. 159) mit a = 862 pm, c = 1 902 pm und Z = 2.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 7-13 
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Complex Fluorides of Divalent PalladiumFor the first time single crystals of the new compounds RbPdPdF5, KPdPdF5, and K2CsPdF5 have been obtained. Orange brown RbPdPdF5 crystallizes orthorhombic, space group Imma-D2h28 (No. 74) with a = 633.6(1) pm, b = 765.5.(1) pm, c = 1067.5(1) pm and Z = 4 and is isotypic with CsPdPdF5 [1]. Structure related KPdPdF5 (also orange brown) crystallizes orthorhombic too, but in space group Pnma-D2h16 (No. 62) with a 614.12(9) pm, b = 748.7(1) pm, c = 1065.0(2) pm and Z = 4. K2CsPdF5, light yellow, crystallizes tetragonal with a = 736.3(1) pm, c = 628.0(1) pm, Z = 2, and is isotypic with Rb2CsPdF5 (space group P4/mbm—D4h5 Nr. 127), an ordered structure variant of the Rb3PdF5-Type [1].
    Notes: Neu dargestellt wurden RbPdPdF5, KPdPdF5 und K2CsPdF5, alle in Form von Einkristallen. Orangebraunes RbPdPdF5 kristallisiert orthorhombisch, R. G. Imma-D2h28 (Nr. 74) mit a = 633,6(1) pm, b = 765,5(1) pm, c = 1067,5(1) pm und Z = 4 und ist isotyp zu CsPdPdF5 [1]. Strukturverwandtes KPdPdF5 (ebenfalls orange-braun) kristallisiert gleichfalls orthorhombisch, jedoch in der R. G. Pma—D2h16 (Nr. 62) mit a = 614,12(9) pm, b = 748,7(1) pm, c = 1065,0(2) pm und Z = 4. K2CsPdF5, hellgelb, kristallisiert tetragonal mit a = 736,3(1) pm, c = 628,0(1) pm Z = 2, ist isotyp zu Rb2CsPdF5 (R. G. P4/mbm—D4h5) (Nr. 127) und somit ein weiterer Vertreter der geordneten Strukturvariante des Rb3PdF5-Typs [1].
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 189-192 
    ISSN: 0044-2313
    Keywords: Fluoropalladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Crystal Structure of LiPdAlF6 and PdZrF6.For the first time single crystals of the new compounds LiPdAlF6 and PdZrF6 have been obtained. LiPdAlF6 (blue) crystallizes trigonal, space group P31c - D3d2 (No. 163; LiCaAlF6-type [2]), in an ordered structure variant of the Li2[ZrF6]-structure [3], with a=497.21(9) pm, c=914.0(9) pm and Z=2. PdZrF6 (also blue) is isotypic with LiSbF6 [4] and crystallizes trigonal-rhomboedric with a=552,3(1) pm, c=1 447,5(4) pm, space group R 3 - C3i2 (No. 148) and Z=3.
    Notes: Neu dargestellt wurden LiPdAlF6 und PdZrF6, beide in Form von Einkristallen. Blaues LiPdAlF6 kristallisiert trigonal im LiCaAlF6-Typ [2], einer Ordnungsvariante der Li2[ZrF6]-Struktur [3], in der Raumgruppe P31c - D3d2 (Nr. 163) mit a=497,21(9) pm, c=914,0(9) pm und Z=2. PdZrF6 (hellblau) kristallisiert trigonal-rhomboedrisch in der Raumgruppe R 3 - C3i2(Nr. 148) mit a=552,3(1) pm, c=1 447,5(4) pm und Z=3 (isotyp zu LiSbF6 [4]).
    Additional Material: 6 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1431-1440 
    ISSN: 0044-2313
    Keywords: Fluoroplatinates(IV) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fluoroplatinates(IV) of the Lanthanides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er)For the first time fluorides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), all yellow have been obtained. From single crystal data they crystallize monoclinic, space group P21/n-C2h5 (No. 14), Z = 4, Pr: a = 1 125.77(19) pm, b = 559.04(7) pm, c = 910.27(17) pm, β = 107.29(1)°; Sm: a = 1 114.63(31) pm, b = 552.70(12) pm, c = 898.02(20) pm, β = 107.24(2)°; Gd: a = 1 112.12(15) pm, b = 551.22(7) pm, c = 891.99(11) pm, β = 107.09(1)°; Tb (Powder data): a = 1 108.88(20) pm, b = 552.71(9) pm, c = 889.56(16) pm, β = 107.30(1)°; Dy: a = 1 100.28(23) pm, b = 547.77(8) pm, c = 882.41(13) pm, β = 107.32(1); Ho: a = 1 099.11(16) pm, b = 546.16(7) pm, c = 879.45(15) pm, β = 107.34(1)°; Er: a = 1 095.10(16) pm, b = 544.82(10) pm, c = 874.85(14) pm, β = 107.37(1)°.
    Notes: Erstmals dargestellt wurden Fluoride LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), alle gelb. Nach Einkristalluntersuchungen kristallisieren diese monoklin in der Raumgruppe P21/n-C2h5 (Nr. 14), Z = 4, Pr: a = 1 125,77(19) pm, b = 559,04(7) pm, c = 910,27(17) pm, β = 107,29(1)°; Sm: a = 1 114,63(31) pm, b = 552,70(12) pm, c = 898,02(20) pm, β = 107,24(2)°; Gd: a = 1 112,12(15) pm, b = 551,22(7) pm, c = 891,99(11) pm, β = 107,09(1)°; Tb (Pulverdaten): a = 1 108,88(20) pm, b = 552,71(9) pm, c = 889,56(16) pm, β = 107,30(1)°; Dy: 1 100,28(23) pm, b = 547,77(8) pm, c = 882,41(13) pm, β = 107,32(1)°; Ho: a = 1 099,11(16) pm, b = 546,16(7) pm, c = 879,45(15) pm, β = 107,34(1)°; Er: a = 1 095,10(16) pm, b = 544,82(10) pm, c = 874,85(14) pm, β = 107,37(1)°. Im Gegensatz zu älteren Befunden liegt die Raumgruppe P21/n-C2h5 (Nr. 14) mit einem verdoppelten Zellvolumen vor.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1969-1972 
    ISSN: 0044-2313
    Keywords: Chromium tetrafluoride ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Structure of Chromium TetrafluorideBy direct fluorination of elemental chromium with a HF/F2-mixture under solvothermal conditions CrF4 has been obtained for the first time in form of single crystal suitable for x-ray investigations. The violet till amethyst coloured CrF4 crystallizes tetragonal, space group P42/mnm-D4h14 (Nr. 136), a = 829.6(1) pm, c = 373.7(1) pm, Z = 4 and is closely related to the NbOCl3-type of structure [1].
    Notes: Durch Druckfluorierung von elementarem Chrom mit einem HF/F2-Gemisch unter Solvothermalbedingungen gelang es erstmals, CrF4 in Form zur Strukturbestimmung geeigneter Einkristalle darzustellen. Das violette bis amethystfarbene, häufig nadelförmige Chromtetrafluorid kristallisiert tetragonal in der Raumgruppe P42/mnm-D4h14 (Nr. 136) mit a = 829,6(1) pm, c = 373,7(1) pm, Z = 4 und ist vom Aufbau her dem NbOCl3-Typ eng verwandt [1].
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