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  • 234Th; C/234Th ratios; carbon export; global; POC  (1)
  • Arctic Ocean  (1)
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  • 1
    Publication Date: 2024-05-11
    Description: The particulate export of photosynthetically fixed carbon from the surface ocean to the ocean interior is a key component of the biological carbon pump and, by extension, of the global carbon cycle. An extensively applied method to estimate the downward flux of particulate carbon is the ²³⁴Th technique, which uses the deficit of ²³⁴Th with respect to its parent, ²³⁸U, coupled with the C/²³⁴Th ratios measured in sinking. More than two decades have passed since the ²³⁴Th technique was first applied to determine the export flux of particulate carbon but the C/²³⁴Th ratio on sinking particles remains as one of the principal uncertainties of this approach. Here we present a global database of 9110 C/²³⁴Th ratios collected using in situ pumps, sediment traps and bottles. Ratios have been grouped, based on the particle size or the device used for the sampling, as: i) Large particles ii) Small particles, iii) Sediment traps and iv) Bulk. The samples were collected between 1989 and 2016 and are distributed among most of the open ocean Longhurst provinces, with some coastal areas also represented. As expected, the data are not evenly distributed along the water column, with most of the data points found in the upper 100-200 m, although the depth range expands from surface down to 〉5500 m. Globally, the ratios range from 0.012 to 1778 µmol/dpm. This database shows how particulate C/²³⁴Th ratios vary with time, depth, particle size and location, which is important for the application of the ²³⁴Th approach and the estimate of the global magnitude of the biological carbon pump.
    Keywords: 234Th; C/234Th ratios; carbon export; global; POC
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © The Authors, 2018. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Roca-Marti, M., Puigcorbe, V., Friedrich, J., van der Loeff, M. R., Rabe, B., Korhonen, M., Camara-Mor, P., Garcia-Orellana, J., & Masque, P. (2018). Distribution of pb-210 and po-210 in the arctic water column during the 2007 sea-ice minimum: Particle export in the ice-covered basins. Deep-Sea Research Part I-Oceanographic Research Papers, 142, 94-106, doi:10.1016/j.dsr.2018.09.011.
    Description: 210Pb and 210Po are naturally occurring radionuclides that are commonly used as a proxy for particle and carbon export. In this study, the distribution of the 210Po/210Pb pair was investigated in the water column of the Barents, Kara and Laptev Seas and the Nansen, Amundsen and Makarov Basins in order to understand the particle dynamics in the Arctic Ocean during the 2007 sea-ice minimum (August-September). Minimum activities of total 210Pb and 210Po were found in the upper and lower haloclines (approx. 60-130 m), which are partly attributed to particle scavenging over the shelves, boundary current transport and subsequent advection of the water with low 210Pb and 210Po activities into the central Arctic. Widespread and substantial (〉50%) deficits of 210Po with respect to 210Pb were detected from surface waters to 200 m on the shelves, but also in the basins. This was particularly important in the Makarov Basin where, despite very low chlorophyll-a levels, estimates of annual new primary production were three times higher than in the Eurasian Basin. In the Nansen, Amundsen and Makarov 32 Basins, estimates of annual new primary production correlated with the deficits of 210Po in the upper 200 m of the water column, suggesting that in situ production and subsequent export of biogenic material were the mechanisms that controlled the removal of 210Po in the central Arctic. Unlike 210Po, 234Th deficits measured during the same expedition were found to be very small and not significant below 25 m in the basins (Cai et al., 2010), which indicates, given the shorter half-life of 234Th, that particle export fluxes in the central Arctic would have been higher before July-August in 2007 than later in the season.
    Description: We would like to thank the crew of the R/V Polarstern and the scientists on board for their cooperation during the ARK-XXII/2 expedition. We greatly appreciate the hard work of Oliver Lechtenfeld who collected and processed the samples on board. Thanks to Dorothea Bauch for sharing her results on freshwater origin and Adam Ulfsbo for providing insightful comments on the estimates of primary production. This project was partly supported by the Ministerio de Ciencia e Innovación (CTM2011-28452, Spain). We wish to acknowledge the support of the Generalitat de Catalunya to the research group MERS (2017 SGR-1588). This work is contributing to the ICTA ‘Unit of Excellence’ (MinECo, MDM2015-0552). M.R.-M. was supported by a Spanish PhD fellowship (AP2010-2510) and an Australian postdoctoral fellowship (2017 Endeavour Research Fellowship).
    Description: 2019-10-22
    Keywords: Particle export ; Annual new primary production ; Scavenging ; 210Po/210Pb ; Arctic Ocean ; 2007 sea-ice minimum
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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