ISSN:
1573-9171
Keywords:
2-(methylthio)pentafluoropropene
;
terminal polyfluoroalkenes
;
[3,3]-sigma-tropic rearrangement
;
deprotonation
;
2-trifluoromethyl-2-methylthiopent-4-enoic acid and its derivatives
;
2-methylthio-2H-trifluoropropionic acid nitrile
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract 2-(Methylthio)pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3 · NEt3 complex. Its reactivity with respect to allyl alcohol and hexamethyldisilazane was studied. The electrophilicity of 2-(methylthio)penta-fluoropropene was compared with the properties of terminal polyfluoroalkenes whose behavior in these reactions has been studied previously.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00699139
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