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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 43 (1994), S. 75-79 
    ISSN: 1573-9171
    Keywords: 2-(methylthio)pentafluoropropene ; terminal polyfluoroalkenes ; [3,3]-sigma-tropic rearrangement ; deprotonation ; 2-trifluoromethyl-2-methylthiopent-4-enoic acid and its derivatives ; 2-methylthio-2H-trifluoropropionic acid nitrile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract 2-(Methylthio)pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3 · NEt3 complex. Its reactivity with respect to allyl alcohol and hexamethyldisilazane was studied. The electrophilicity of 2-(methylthio)penta-fluoropropene was compared with the properties of terminal polyfluoroalkenes whose behavior in these reactions has been studied previously.
    Type of Medium: Electronic Resource
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