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  • 170-1039B; 170-1039C; 170-1040C; 205-1253A; 205-1254A; 205-1255A; Costa Rica subduction complex, North Pacific Ocean; DRILL; Drilling/drill rig; Joides Resolution; Leg170; Leg205; North Pacific Ocean; Ocean Drilling Program; ODP  (1)
  • Methane  (1)
  • 2005-2009  (2)
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  • 2005-2009  (2)
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  • 1
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    PANGAEA
    In:  Supplement to: Kastner, Miriam; Solomon, Evan A; Wei, Wei; Chan, Lui-Heung; Saether, Ola M (2006): Data report: Chemical and isotopic compositions of pore fluids and sediments from across the Middle America Trench, offshore Costa Rica. In: Morris, JD; Villinger, HW; Klaus, A (eds.) Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 205, 1-21, https://doi.org/10.2973/odp.proc.sr.205.208.2006
    Publication Date: 2024-01-09
    Description: Pore fluid and sediment chemical and isotopic data were obtained for samples from Ocean Drilling Program (ODP) Leg 205 Sites 1253, 1254, and 1255 in the Costa Rica subduction zone. The chemical and isotopic data reported here were generated in our shore-based laboratories to complement shipboard inorganic geochemical data. Li isotopic analyses were carried out by L.-H. Chan at Louisiana State University (USA). The data reported herein include fluoride, bromide, rubidium, cesium, and barium concentrations; Li and Sr isotopic compositions in pore fluids; and Rb, Cs, and Ba concentrations in representative bulk sediments. The data also include new pore fluid fluoride and bromide concentrations from corresponding ODP Leg 170 Sites 1039, 1040, and 1043. O.M. Saether's Site 1039 and 1040 fluoride concentration data are shown for comparison. Basal sediment fluoride concentrations and Li and Sr isotope ratios at both Sites 1253 and 1039 show reversals that approach modern seawater values. Br/Cl ratios are, however, conservative throughout the sediment section at Sites 1039 and 1253. The observed sharp F and Br concentration maxima, Rb and K concentration minima, the most radiogenic 87Sr/86Sr ratios, and highest 7Li values along the décollement and fracture zone (Sites 1040, 1043, 1254, and 1255) strengthen the evidence obtained during Leg 170 that a deeply sourced fluid, originating from fluid-rock reactions at ~150°C and corresponding to between 10 and 15 km depth, is transporting solutes to the ocean.
    Keywords: 170-1039B; 170-1039C; 170-1040C; 205-1253A; 205-1254A; 205-1255A; Costa Rica subduction complex, North Pacific Ocean; DRILL; Drilling/drill rig; Joides Resolution; Leg170; Leg205; North Pacific Ocean; Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 2 datasets
    Location Call Number Expected Availability
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 267 (2008): 341-352, doi:10.1016/j.epsl.2007.11.053.
    Description: Detailed near-bottom investigation of a series of giant, kilometer scale, elongate pockmarks along the edge of the mid-Atlantic continental shelf confirms that methane is actively venting at the site. Dissolved methane concentrations, which were measured with a commercially available methane sensor (METS) designed by Franatech GmbH mounted on an autonomous underwater vehicle (AUV), are as high as 100 nM. These values are well above expected background levels (1-4 nM) for the open ocean. Sediment pore water geochemistry gives further evidence of methane advection through the seafloor. Isotopically light carbon in the dissolved methane samples indicates a primarily biogenic source. The spatial distribution of the near-bottom methane anomalies (concentrations above open ocean background), combined with water column salinity and temperature vertical profiles, indicate that methane-rich water is not present across the entire width of the pockmarks, but is laterally restricted to their edges. We suggest that venting is primarily along the top of the pockmark walls with some advection and dispersion due to local currents. The highest methane concentrations observed with the METS sensor occur at a small, circular pockmark at the southern end of the study area. This observation is compatible with a scenario where the larger, elongate pockmarks evolve through coalescing smaller pockmarks.
    Description: This work was supported by NSF grants OCE- 0242426, OCE-0242804 and OCDE-0242449 and ONR grant N00014-02-1-0691.
    Keywords: Pockmarks ; Seafloor venting ; Methane ; AUV
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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