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  • 165-1000A; AGE; Caribbean Sea; Comment; DEPTH, sediment/rock; DRILL; Drilling/drill rig; ICP-OES, Inductively coupled plasma - optical emission spectrometry; Joides Resolution; LA-ICP-MS, Laser-ablation inductively coupled plasma mass spectrometer; Leg165; Magnesium/Calcium ratio; Number; Number of profiles; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; Sample code/label; SPP1158; Strontium/Calcium ratio  (1)
  • Oxygen isotopes
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA3219, doi:10.1029/2011PA002132.
    Description: Shell chemistry of planktic foraminifera and the alkenone unsaturation index in 69 surface sediment samples in the tropical eastern Indian Ocean off West and South Indonesia were studied. Results were compared to modern hydrographic data in order to assess how modern environmental conditions are preserved in sedimentary record, and to determine the best possible proxies to reconstruct seasonality, thermal gradient and upper water column characteristics in this part of the world ocean. Our results imply that alkenone-derived temperatures record annual mean temperatures in the study area. However, this finding might be an artifact due to the temperature limitation of this proxy above 28°C. Combined study of shell stable oxygen isotope and Mg/Ca ratio of planktic foraminifera suggests that Globigerinoides ruber sensu stricto (s.s.), G. ruber sensu lato (s.l.), and G. sacculifer calcify within the mixed-layer between 20 m and 50 m, whereas Globigerina bulloides records mixed-layer conditions at ∼50 m depth during boreal summer. Mean calcifications of Pulleniatina obliquiloculata, Neogloboquadrina dutertrei, and Globorotalia tumida occur at the top of the thermocline during boreal summer, at ∼75 m, 75–100 m, and 100 m, respectively. Shell Mg/Ca ratios of all species show a significant correlation with temperature at their apparent calcification depths and validate the application of previously published temperature calibrations, except for G. tumida that requires a regional Mg/Ca-temperature calibration (Mg/Ca = 0.41 exp (0.068*T)). We show that the difference in Mg/Ca-temperatures of the mixed-layer species and the thermocline species, particularly between G. ruber s.s. (or s.l.) and P. obliquiloculata, can be applied to track changes in the upper water column stratification. Our results provide critical tools for reconstructing past changes in the hydrography of the study area and their relation to monsoon, El Niño-Southern Oscillation, and the Indian Ocean Dipole Mode.
    Description: This project was funded by the German Ministry of Education and Research (BMBF project PABESIA) and the “Deutsche Forschungsgemeinschaft” (DFG project HE 3412/15–1).
    Keywords: Indian Ocean ; Mg/Ca ; Alkenone ; Oxygen isotopes ; Planktic foraminifera ; Thermal structure
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Format: image/tiff
    Format: text/plain
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  • 2
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    PANGAEA
    In:  Supplement to: Groeneveld, Jeroen; Nürnberg, Dirk; Tiedemann, Ralf; Reichart, Gert-Jan; Steph, Silke; Reuning, Lars; Crudeli, Daniela; Mason, P (2008): Foraminiferal Mg/Ca increase in the Caribbean during the Pliocene: Western Atlantic Warm Pool formation, salinity influence, or diagenetic overprint? Geochemistry, Geophysics, Geosystems, 9, Q01P23, https://doi.org/10.1029/2006GC001564
    Publication Date: 2023-10-28
    Description: We constructed a high-resolution Mg/Ca record on the planktonic foraminifer Globigerinoides sacculifer in order to explore the change in sea surface temperature (SST) due to the shoaling of the Isthmus of Panama as well as the impact of secondary factors like diagenesis and large salinity fluctuations. The study covers the latest Miocene and the early Pliocene (5.6-3.9 Ma) and was combined with d18O to isolate changes in sea surface salinity (SSS). Before 4.5 Ma, SSTMg/Ca and SSS show moderate fluctuations, indicating a free exchange of surface ocean water masses between the Pacific and the Atlantic. The increase in d18O after 4.5 Ma represents increasing salinities in the Caribbean due to the progressive closure of the Panamanian Gateway. The increase in Mg/Ca toward values of maximum 7 mmol/mol suggests that secondary influences have played a significant role. Evidence of crystalline overgrowths on the foraminiferal tests in correlation with aragonite, Sr/Ca, and productivity cyclicities indicates a diagenetic overprint on the foraminiferal tests. Laser ablation inductively coupled plasma-mass spectrometry analyses, however, do not show significantly increased Mg/Ca ratios in the crystalline overgrowths, and neither do calculations based on pore water data conclusively result in significantly elevated Mg/Ca ratios in the crystalline overgrowths. Alternatively, the elevated Mg/Ca ratios might have been caused by salinity as the d18O record of Site 1000 has been interpreted to represent large fluctuations in SSS, and cultivating experiments have shown an increase in Mg/Ca with increasing salinity. We conclude that the Mg/Ca record 〈4.5 Ma can only reliably be considered for paleoceanographical purposes when the minimum values, not showing any evidence of secondary influences, are used, resulting in a warming of central Caribbean surface water masses after 4.5 Ma of ~2°C.
    Keywords: 165-1000A; AGE; Caribbean Sea; Comment; DEPTH, sediment/rock; DRILL; Drilling/drill rig; ICP-OES, Inductively coupled plasma - optical emission spectrometry; Joides Resolution; LA-ICP-MS, Laser-ablation inductively coupled plasma mass spectrometer; Leg165; Magnesium/Calcium ratio; Number; Number of profiles; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; Sample code/label; SPP1158; Strontium/Calcium ratio
    Type: Dataset
    Format: text/tab-separated-values, 32 data points
    Location Call Number Expected Availability
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