ALBERT

Description: © The Author(s), 2017. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Chemical Geology 465 (2017): 35-51, doi:10.1016/j.chemgeo.2017.05.020.

Description: During the Integrated Ocean Drilling Program (IODP) Expedition 331, five sites were drilled into the Iheya North Knoll hydrothermal system in the Okinawa Trough (OT) — a back-arc basin characterized by thick terrigenous sediment. Following up on the previous study by Shao et al. (2015), we present new mineralogical, geochemical, and Sr-Nd isotope data to investigate the origin of the hydrothermal sediments and characterize the hydrothermal system. The substrate at the Iheya North Knoll is dominated by pumiceous sediment and other volcanoclastic materials interbedded with hemipelagic (terrigenous and biogenous) sediments. Impermeable layers separate the hydrothermal sediments into distinct units with depth that are characterized by various assemblages of alteration materials, including polymetallic sulfides, sulfates, chlorite- and kaolinite-rich sediments. The rare earth elements (REEs) and Nd isotope data suggest that the chlorite-rich and kaolinite-rich layers primarily resulted from the alteration of pumiceous materials in different chemical and physical conditions. Kaolinite-rich sediment likely reflects low pH and low Mg concentration fluids, while chlorite-rich sediment formed from fluids with high pH and increased Mg contents, likely at higher temperatures. The Sr isotopic compositions of subsurface anhydrite reflect high seawater/hydrothermal fluid ratios in the mid-OT hydrothermal area. Compared with chlorite-rich sediments from other sediment-covered or felsic-hosted hydrothermal systems, the chlorite-rich sediments in the mid-OT are characterized by lower concentrations of Al and Fe but much higher Y, Zr, Hf, Th and REEs, indicative of the distinct nature of the precursor rocks in this region.

Description: This work was supported by the National Natural Science Foundation of China (Grant Nos. 41376049 and 41225020), National Programme on Global Change and Air-Sea Interaction (GASI-GEOGE-03), AoShan Talents Program Supported by Qingdao National Laboratory for Marine Science and Technology (No. 2015ASTP-OS11), Program of Shanghai Subject Chief Scientist (No. 14XD1403600), and Continental Shelf Drilling Program (No. GZH201100202).

Description: Strontium- and oxygen-isotopic measurements of samples recovered from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound during Leg 158 of the Ocean Drilling Program provide important constraints on the nature of fluid–rock interactions during basalt alteration and mineralization within an active hydrothermal deposit. Fresh Mid-Ocean Ridge Basalt (MORB), with a 87Sr/86Sr of 0.7026, from the basement beneath the TAG mound was altered at both low and high temperatures by seawater and altered at high temperature by near end-member black smoker fluids. Pillow breccias occurring beneath the margins of the mound are locally recrystallized to chlorite by interaction with large volumes of conductively heated seawater (〉200°C). The development of a silicified, sulfide-mineralized stockwork within the basaltic basement follows a simple paragenetic sequence of chloritization followed by mineralization and the development of a quartz+pyrite+paragonite stockwork cut by quartz–pyrite veins. Initial alteration involved the development of chloritic alteration halos around basalt clasts by reaction with a Mg-bearing mixture of upwelling, high-temperature (〉300°C), black smoker-type fluid with a minor (〈10%) proportion of seawater. Continued high-temperature (〉300°C) interaction between the wallrock and these Mg-bearing fluids results in the complete recrystallization of the wallrock to chlorite+quartz+pyrite. The quartz+pyrite+paragonite assemblage replaces the chloritized basalts, and developed by reaction at 250–360°C with end-member hydrothermal fluids having 87Sr/86Sr ~0.7038, similar to present-day vent fluids. The uniformity of the 87Sr/86Sr ratios of hydrothermal assemblages throughout the mound and stockwork requires that the 87Sr/86Sr ratio of end-member hydrothermal fluids has remained relatively constant for a time period longer than that required to change the interior thermal structure and plumbing network of the mound and underlying stockwork. Precipitation of anhydrite in breccias and as late-stage veins throughout most of the mound and stockwork, down to at least 125 mbsf, records extensive entrainment of seawater into the hydrothermal deposit. 87Sr/86Sr ratios indicate that most of the anhydrite formed from ~2:1 mixture of seawater and black smoker fluids (65%±15% seawater). Oxygen-isotopic compositions imply that anhydrite precipitated at temperatures between 147°C and 270°C and require that seawater was conductively heated to between 100°C and 180°C before mixing and precipitation occurred. Anhydrite from the TAG mound has a Sr–Ca partition coefficient Kd ~0.60±0.28 (2 sigma). This value is in agreement with the range of experimentally determined partition coefficients (Kd ~0.27–0.73) and is similar to those calculated for anhydrite from active black smoker chimneys from 21°N on the East Pacific Rise. The d18O (for SO4) of TAG anhydrite brackets the value of seawater sulfate oxygen (~9.5‰). Dissolution of anhydrite back into the oceans during episodes of hydrothermal quiescence provides a mechanism of buffering seawater sulfate oxygen to an isotopically light composition, in addition to the precipitation and dissolution of anhydrite within the oceanic basement during hydrothermal recharge at the mid-ocean ridges.