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Conformational dependence of 13C SCS in 1-methyl-1-phenylcyclohexanes (1987)

Cook, Michael J. ; Nasri, Khalida A.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 25 (1987), S. 644-647

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ISSN: 0749-1581

Keywords: 13C NMR ; 1-methyl-1-phenylcyclohexanes ; 13C SCS - conformational dependence ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 13C chemical shift data are reported for a series of para-substituted 1-methyl-1-phenylcyclohexanes at 22 and -100 °C. The magnitudes of the SCS at alkyl and cycloalkyl carbon positions are discussed. The SCS at C-methyl and C-4 are significantly different in the two chair conformations. The variation at C-methyl is appraised in terms of the orientation of the aromatic ring.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260250717

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