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  • 108-664C; 108-668B; 130-806A; 138-847B; 138-851B; 154-925B; 165-999A; Agadir Canyon; BOFS11891#4; BOFS11905#1; BOFS11K; BOFS17K; Cape Basin; Caribbean Sea; D184; Discovery (1962); DRILL; Drilling/drill rig; GeoB1208-2; GeoB4216-1; Gravity corer (Kiel type); Joides Resolution; KAL; Kasten corer; Leg108; Leg130; Leg138; Leg154; Leg165; M12/1; M37/1; Meteor (1986); Northeast Atlantic; North Pacific Ocean; Ocean Drilling Program; ODP; SL; South Atlantic Ocean  (1)
  • MPT
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  • 1
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    PANGAEA
    In:  Supplement to: Foster, Gavin L (2008): Seawater pH, pCO2 and [CO3 [2-] ] variations in the Caribbean Sea over the last 130 kyr: A boron isotope and B/Ca study of planktic foraminifera. Earth and Planetary Science Letters, 271(1-4), 254-266, https://doi.org/10.1016/j.epsl.2008.04.015
    Publication Date: 2024-02-02
    Description: Here a new analytical methodology is described for measuring the isotopic composition of boron in foraminifera using multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). This new approach is fast (~10 samples analysed in duplicate per analytical session) and accurate (to better than 0.25 per mil at 95% confidence) with acceptable sample size requirements (1-3 mg of carbonate). A core top calibration of several common planktic and two benthic species from geographically widespread localities shows a very close agreement between the isotopic composition measured by MC-ICPMS and the isotopic composition of B(OH)-4 in seawater (as predicted using the recently measured isotopic equilibrium factor of 1.0272) at the depth of habitat. A down core and core top investigation of boron concentration (B/Ca ratio) shows that the partition coefficient is influenced by [CO2-3] complicating the application of this proxy. Nevertheless, it is demonstrated that these two proxies can be used to fully constrain the carbonate system of surface water in the Caribbean Sea (ODP Site 999A) over the last 130 kyr. This reconstruction shows that during much of the Holocene and the last interglacial period surface water at Site 999A was in equilibrium with the atmosphere with respect to CO2. During the intervening colder periods although the surface water pCO2 was lower than the Holocene, it was a minor to significant source of CO2 to the atmosphere possibly due to either an expansion of the eastern equatorial Atlantic upwelling zone, or a more local expansion of coastal upwelling in the southern Caribbean. Such reorganisation of the oceanic carbonate system in favour of a larger source of CO2 to the atmosphere from the equatorial ocean may require mechanisms responsible for lowering atmospheric CO2 during glacial periods to be more efficient than previously supposed.
    Keywords: 108-664C; 108-668B; 130-806A; 138-847B; 138-851B; 154-925B; 165-999A; Agadir Canyon; BOFS11891#4; BOFS11905#1; BOFS11K; BOFS17K; Cape Basin; Caribbean Sea; D184; Discovery (1962); DRILL; Drilling/drill rig; GeoB1208-2; GeoB4216-1; Gravity corer (Kiel type); Joides Resolution; KAL; Kasten corer; Leg108; Leg130; Leg138; Leg154; Leg165; M12/1; M37/1; Meteor (1986); Northeast Atlantic; North Pacific Ocean; Ocean Drilling Program; ODP; SL; South Atlantic Ocean
    Type: Dataset
    Format: application/zip, 2 datasets
    Location Call Number Expected Availability
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  • 2
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Proceedings of the National Academy of Sciences of the United States of America 114 (2017): 13114-13119, doi: 10.1073/pnas.1702143114.
    Description: During the Mid-Pleistocene Transition (MPT; 1,200–800 kya), Earth’s orbitally paced ice age cycles intensified, lengthened from ∼40,000 (∼40 ky) to ∼100 ky, and became distinctly asymmetrical. Testing hypotheses that implicate changing atmospheric CO2 levels as a driver of the MPT has proven difficult with available observations. Here, we use orbitally resolved, boron isotope CO2 data to show that the glacial to interglacial CO2 difference increased from ∼43 to ∼75 μatm across the MPT, mainly because of lower glacial CO2 levels. Through carbon cycle modeling, we attribute this decline primarily to the initiation of substantive dust-borne iron fertilization of the Southern Ocean during peak glacial stages. We also observe a twofold steepening of the relationship between sea level and CO2-related climate forcing that is suggestive of a change in the dynamics that govern ice sheet stability, such as that expected from the removal of subglacial regolith or interhemispheric ice sheet phase-locking. We argue that neither ice sheet dynamics nor CO2 change in isolation can explain the MPT. Instead, we infer that the MPT was initiated by a change in ice sheet dynamics and that longer and deeper post-MPT ice ages were sustained by carbon cycle feedbacks related to dust fertilization of the Southern Ocean as a consequence of larger ice sheets.
    Description: Research was supported by National Environmental Research Council (NERC) Studentship NE/I528626/1 (to T.B.C.); NERC Grant NE/P011381/1 (to T.B.C., M.P.H., G.L.F., E.J.R., and P.A.W.); NERC Fellowships NE/K00901X/1 (to M.P.H.), NE/I006346/1 (to G.L.F. and R.D.P), and NE/H006273/1 (to R.D.P.); Royal Society Wolfson Awards (to G.L.F. and P.A.W.); Australian Research Council Laureate Fellowship FL1201000050 (to E.J.R.); Swiss National Science Foundation Grant PP00P2-144811 (to S.L.J.); ETH Research Grant ETH-04 11-1 (to S.L.J.); European Research Council Consolidator Grant (ERC CoG) Grant 617462 (to H.P.); and NERC UK IODP Grant NE/F00141X/1 (to P.A.W.).
    Keywords: Boron isotopes ; MPT ; Geochemistry ; Carbon dioxide ; Paleoclimate
    Repository Name: Woods Hole Open Access Server
    Type: Article
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