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  • 103-638B; 103-640A; 103-641A; 103-641C; DRILL; Drilling/drill rig; Joides Resolution; Leg103; Ocean Drilling Program; ODP; South Atlantic Ocean  (1)
  • Chromans
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  • 1
    ISSN: 1573-1421
    Keywords: Chromans ; homohopenes ; isoprenoid thiolanes ; isoprenoid thiophenes ; methylated MTTC ; Nördlinger Ries ; tocopherols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Distributions of alkylated chromans and C20 isoprenoid thiophenes were investigated in four organic-matter- and sulfur-rich black shales of Miocene age deposited in the ancient crater lake of the Nördlinger Ries (southern Germany), a meteorite impact crater. Paleosalinity parameters based on these compound classes generally confirm sedimentological evidence of increased salinity over certain periods of the lake's history, but the data from both groups of compounds are not consistent. Diagenetically related molecular constituents were therefore studied to estimate the sensitivity of these parameters. The influence of thiolanes on the isoprenoid thiophene parameter was found to be low, whereas too little is known at present about the origin and diagenetic fate of alkylated chromans to conclude definitely that an alkylated chroman paleosalinity parameter can reliably be applied to a wide range of depositional settings.
    Type of Medium: Electronic Resource
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  • 2
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    In:  Supplement to: Stein, Ruediger; Rullkötter, Jürgen; Littke, Ralf; Schaefer, Rainer G; Welte, Dietrich Hugo (1988): Organofacies reconstruction and lipid geochemistry of sediments from the Galicia margin, Northeast Atlantic (ODP Leg 103). In: Boillot, G; Winterer, EL; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 103, 567-585, https://doi.org/10.2973/odp.proc.sr.103.158.1988
    Publication Date: 2024-01-09
    Description: Samples of Lower to middle Cretaceous rocks from ODP Sites 638, 640, and 641, drilled on the Galicia continental margin in the northeast Atlantic, have been investigated by organic geochemical methods (i.e., organic carbon determination, Rock-Eval pyrolysis, kerogen microscopy, gas chromatography, and gas chromatography/mass spectrometry) to define the Organofacies types and the depositional environments of these sediments. The results of this study fit well into the general picture drawn for the depositional history of the organic matter in Cretaceous organic-carbon-rich sediments in the North Atlantic from previous DSDP investigations. During the Valanginian to Albian, terrigenous organic carbon dominated the organic matter deposited on the Galicia continental margin. Cyclic changes in total organic carbon content were probably controlled by climatic-triggered changes in the supply of terrigenous organic matter from the nearby continent. A drastic change in depositional environment must have occurred near the Cenomanian/Turonian boundary. The preservation of large amounts of marine organic carbon in these sediments was probably caused by anoxic deep-water conditions during that time, rather than high productivity. All of the primary organic matter of the sediment samples investigated is thermally immature, as indicated by very low vitrinite reflectance values.
    Keywords: 103-638B; 103-640A; 103-641A; 103-641C; DRILL; Drilling/drill rig; Joides Resolution; Leg103; Ocean Drilling Program; ODP; South Atlantic Ocean
    Type: Dataset
    Format: application/zip, 4 datasets
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