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Zur Struktur von Trithiatriazinen (1990)

Jaudas-Prezel, Evelyn ; Maggiulli, Roberto ; Mews, Rüdiger ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 2117-2122

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ISSN: 0009-2940

Keywords: 1λ4,3λ4,5λ4-Trithiatriazines ; Anomeric effect ; Antiaromaticity ; Calculations, ab initio, MNDO ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The Structure of TrithiatriazinesMNDO and ab initio calculations have shown that the structure of trithiatriazines [(RSN)3, where R = F, Cl, {H}] is influenced by the anomeric effect and by antiaromaticity of the ring for electron pairs in axial positions. These calculations are supported by a joint electron diffraction and microwave structure determination of (NSF)3 in the gas phase.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19901231106

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