ISSN:
0009-2940
Keywords:
Stannylene, bis(2,4,6-triisopropylphenyl)-
;
Distannene, tetrakis(2,4,6-triisopropylphenyl)-
;
1,2-Distannacyclobutene derivative
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Compounds of Germanium and Tin, 10[1]. - Thermolysis of a Cyclotristannane: Stannylene versus Distannene ReactionsHexakis(2,4,6-triisopropylphenyl)cyclotristannane (1), first described by Masamune and Sita, is easily accessible by treatment of tin(II) chloride with 2,4,6-triisopropylphenylmagnesium bromide. The equilibrium between 1 and its cleavage products bis(2,4,6-triisopropylphenyl)stannylene (2) and tetrakis(2,4,6-triisopropylphenyl)distannene (3) in toluene has been followed by 119Sn-NMR spectroscopy at elevated temperatures. Stannylene 2 can be trapped by open-chain or cyclic diketones as well as by 1,3-dienes. Reaction of 3 with phenylacetylene proceeds in a [2 + 2] fashion to provide the 1,2-distannacyclobutene derivative 5 whose structure was confirmed by X-ray crystallography.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250306
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