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Novel four-membered silicon-phosphorus-containing heterocycles (1993)

Monin, E. A. ; Bykova, I. A. ; Chernyshev, E. A.

Springer

Russian chemical bulletin 42 (1993), S. 954-955

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ISSN: 1573-9171

Keywords: four-membered silicon-phosphorus-containing heterocycles, synthesis ; 1,2-λ3,4-azaphosphasiletidines

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Four-membered heterocycles have been prepared by the reaction of (methyldichlorosilyl)- and (dimethylchlorosilyl)methyldichlorophosphines with primary aliphatic amines: 1,2λ3,4-azaphosphasiletidines and acyclic (methylaminosilyl)methyldiamidophosphonites. The latter eliminate primary amines on heatingin vacuo to give 1,2λ3,4-azaphosphasiletidines. The structures of the compounds thus obtained have been studied by31P,29Si,1H, and13C NMR.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00698971

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