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  • 1
    Publication Date: 2024-03-26
    Description: Mafic alkaline magmas, such as those feeding the persistent eruptive activity of Stromboli and Mt. Etna volcanoes in Italy, are dominated by the crystallization of plagioclase via cooling and degassing phenomena related to the dynamics of shallow crustal reservoirs and eruptive conduits. Because plagioclase textures and compositions are extremely sensitive to the changes of intensive variables in subvolcanic plumbing systems, the phenomenological variability of erupted crystals preserves detailed evidence of complex growth histories. From this point of view, we reappraise the textural maturation and compositional complexity of plagioclase by allying thermodynamic and kinetic principles to natural and experimental observations, with the purpose of drawing up guidelines for reconstructing magma dynamics in mafic alkaline volcanic settings. A multifaceted statistical method is adopted to parameterize the decay of crystal growth rate with increasing crystallization time, as relaxation kinetics prevails over melt supersaturation effects. This model parameterization is combined with the textural analysis of natural plagioclase crystals to quantify the residence time of phenocrysts in equilibrium with magmas at Stromboli and Mt. Etna and/or the timescale of rapid microlite growth during disequilibrium ascent of magmas within the conduit. The role played by temperature and melt-water content on plagioclase components and major cation substitution mechanisms is also evaluated under both isobaric-isothermal and decompression conditions. The emerging paradigm is that the influence of dissolved water on anorthite-albite exchange between plagioclase and melt is overwhelmingly mitigated by changes in temperature at conditions of P = 30–300 MPa, T = 1050–1150 °C, fO2 = NNO + 1.9-NNO + 2.3, and melt-H2O = 0.6–4.4 wt%. As a corollary, anorthite and albite melt activities are almost fully encapsulated in the variation of anhydrous melt components as the crystallization of plagioclase proceeds during magma cooling. Following this line of reasoning, we propose an integrated modeling approach to decipher complex zoning patterns in natural plagioclase phenocrysts from mafic alkaline eruptions. Key findings from our re-assessment of equilibrium, thermometric, and hygrometric models indicate that temperature and dissolved water can be iteratively estimated for different plagioclase textural patterns if crystals are sufficiently strongly zoned and probability-based criteria are applied to determine the maximum probability distribution from kernel density analysis.
    Description: Natural Environment research Council UK grant NE/T009292/1; INGV Progetti Ricerca Libera 2019 Grant #52/2020; INGV Departmental Strategic Project UNO; PRIN MIUR Grant #2017J277S9_004.
    Description: Published
    Description: 104399
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Mafic alkaline magmas ; Plagioclase growth rate parameterization ; Plagioclase-based thermometry and hygrometry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-03-13
    Description: The peninsular and insular Italy are punctuated by Quaternary volcanoes and their rocks constitute an important aliquot of the Italian Quaternary sedimentary successions. Also away from volcanoes itself, volcanic ash layers are a common and frequent feature of the Quaternary records, which provide us with potential relevant stratigraphic and chronological markers at service of a wide array of the Quaternary science issues. In this paper, a broad representation of the Italian volcanological community has joined to provide an updated comprehensive state of art of the Italian Quaternary volcanism. The eruptive history, style and dynamics and, in some cases, the hazard assessment of about thirty Quaternary volcanoes, from the northernmost Mt. Amiata, in Tuscany, to the southernmost Pantelleria, in Sicily Channel, are here reviewed in the light of the substantial improving of the conceptual models, methodological approaches and the overall knowledge made in the last decades in the volcanological field study. We hope that the prest review can represent an useful and agile document summarising the knowledege on the Italian volcanism at the service of the Quaternary community operating in central Mediterranean area.
    Description: Published
    Description: 221-284
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: N/A or not JCR
    Keywords: Stratigraphy, Geochronology, geochemistry, Quaternary volcanism, eruptive history, Italy ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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