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  • 1
    Publication Date: 2021-02-12
    Description: We have carried out a detailed petrological investigation on products of the poorly understood Nisida eruption, one of the most recent volcanic events (~4 ka BP) at Campi Flegrei caldera. We present major oxide contents and Sr–Nd isotopic data determined on bulk rock, groundmass and separated phenocrysts, along with major and volatile elements (H2O Cl, S and CO2) content of clinopyroxene-hosted melt inclusions from pumice fragments representative of the eruption. We use these to elaborate the role of magmatic evolution processes and fluid transfer prior to, and during, the Nisida eruption.The results indicate that the eruption was triggered by the arrival of a volatile-rich, shoshonite–latite magma. This magma was similar in terms of Sr and Nd isotopes (87Sr/86Sr ~0.70730; 143Nd/144Nd ~0.51250) to the Astroni 6 magmatic component. We infer that emplacement of this magma triggered resurgence of the caldera floor, and fed a large part of the volcanic activity at Campi Flegrei caldera during the past 5 ka. The new data on the Nisida eruption and other recent eruptions at Campi Flegrei, together with published data, suggest that fractional crystallization, and potentially fluid transfer from deep to shallow depths may account for most of the chemical variability of the erupted melt. Additional processes, such as magma mingling/mixing, and/or entrapment of antecrysts into the magma prior to the Nisida eruption are required to explain the large isotopic variation displayed by the analyzed products. The Nisida eruption occurred in the eastern sector of the resurgent Campi Flegrei caldera. In this sector, presently affected by an extensional stress regime, previous studies suggest that a Nisida-like eruption would be likely if the level of activity in the caldera were to intensify. In an area with such structural conditions, the ascent of a volatilerich magma such as that which erupted at Nisida should generate geophysical and geochemical signals detectable by an efficient monitoring network. The results of this investigation should inform the study of other active calderas worldwide that are experiencing persistent unrest, such as Rabaul, Aira, Iwo-Jima, Santorini, Long Valley and Yellowstone.
    Description: Published
    Description: 109-124
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Campi Flegrei ; Sr and Nd isotopes ; Magma chamber processes ; Melt inclusions ; Fluid transfer ; Volcanic unrest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-06-03
    Description: We present here the first volcanic gas compositional time-series taken prior to a paroxysmal eruption of Villarrica volcano (Chile). Our gas plume observations were obtained using a fully autonomous Multi-component Gas Analyser System (Multi-GAS) in the 3 month-long phase of escalating volcanic activity that culminated into the 3 March 2015 paroxysm, the largest since 1985. Our results demonstrate a temporal evolution of volcanic plume composition, from low CO2/SO2 ratios (0.65-2.7) during November 2014-January 2015 to CO2/SO2 ratios up to 9 then after. The H2O/CO2 ratio simultaneously declined to 〈38 in the same temporal interval. We use results of volatile saturation models to demonstrate that this evolution toward CO2-enriched gas was likely caused by unusual supply of deeply sourced gas bubbles. We propose that separate ascent of over-pressured gas bubbles, originating from at least 20-35 MPa pressures, was the driver for activity escalation toward the 3 March climax
    Description: Published
    Description: 2120–2132
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2020-06-03
    Description: Volcanic unrest at calderas involves complex interaction between magma, hydrothermal fluids, and crustal stress and strain. Campi Flegrei caldera (CFc), located in the Naples (Italy) area and characterized by the highest volcanic risk on Earth for the extreme urbanization, undergoes unrest phenomena involving several meters of uplift and intense shallow microseismicity since several decades. Despite unrest episodes display in the last decade only moderate ground deformation and seismicity, current interpretations of geochemical data point to a highly pressurized hydrothermal system. We show that at CFc, the usual assumption of vapor-liquid coexistence in the fumarole plumes leads to largely overestimated hydrothermal pressures and, accordingly, interpretations of elevated unrest. By relaxing unconstrained geochemical assumptions, we infer an alternative model yielding better agreement between geophysical and geochemical observations. The model reconciles discrepancies between what observed (1) for two decades since the 1982–1984 large unrest, when shallow magma was supplying heat and fluids to the hydrothermal system, and (2) in the last decade. Compared to the 1980’s unrest, the post-2005 phenomena are characterized by much lower aquifers overpressure and magmatic involvement, as indicated by geophysical data and despite large changes in geochemical indicators. Our interpretation points out a model in which shallow sills, intruded during 1969–1984, have completely cooled, so that fumarole emissions are affected now by deeper, CO2-richer, magmatic gases producing the modest heating and overpressure of the hydrothermal system. Our results have important implications on the short-term eruption hazard assessment and on the best strategies for monitoring and interpreting geochemical data.
    Description: Published
    Description: 1244–1269
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2022-05-02
    Description: magmatic volatiles
    Description: Published
    Description: 431-556
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Keywords: silicate melts ; thermodynamic modeling ; volcanic gases ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 5
    Publication Date: 2023-01-20
    Description: Abstract By using a permanent network of multi-component gas analyzer systems (Multi-GAS), we report for the first time the H2O-CO2-SO2 composition of the volcanic gases emitted prior to, during, and after terminal Strombolian activity at Mount Etna’s central craters (CCs). We show that the summer 2012 Strombolian episodes of the Bocca Nuova crater (BNC), the largest of Etna’s CCs, are associated with the emission of the most CO2-rich gas measured at the volcano thus far. The BNC plume was particularly CO2-rich with CO2/SO2 up to 100, H2O/CO2 〈 1 in the quiescent periods between Strombolian episodes. However, more CO2-poor gas with CO2/SO2 〈 27, H2O/CO2 〉 1 prevailed at the BNC and at other degassing vents such as Voragine and Northeast craters during Strombolian eruptions. Based on the results of numerical simulations of volcanic degassing, conclude that the shallow Etna plumbing system was invaded in summer 2012 by a CO2-rich gas front likely supplied by the deep (〉100 MPa pressure) volcano’s magmatic storage zone. This deep gas-bubble supply eventually caused a general rejuvenation of the resident magma in the upper conduits/shallow reservoirs, thereby triggering the first Strombolian episodes on the volcano’s summit after years of quiescence.
    Description: Published
    Description: 123-138
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: volcanic gases ; Etna ; degassing ; Multi-GAS ; volcano monitoring ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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