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  • 04.01. Earth Interior  (2)
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  • 1
    Publication Date: 2021-02-05
    Description: Understanding the viscosity of mantle-derived magmas is needed to model their migration mechanisms and ascent rate from the source rock to the surface. High pressure–temperature experimental data are now available on the viscosity of synthetic melts, pure carbonatitic to carbonate–silicate compositions, anhydrous basalts, dacites and rhyolites. However, the viscosity of volatile-bearing melilititic melts, among the most plausible carriers of deep carbon, has not been investigated. In this study, we experimentally determined the viscosity of synthetic liquids with ~31 and ~39 wt% SiO2, 1.60 and 1.42 wt% CO2 and 5.7 and 1 wt% H2O, respectively, at pressures from 1 to 4.7 GPa and temperatures between 1265 and 1755 C, using the falling-sphere technique combined with in situ X-ray radiography. Our results show viscosities between 0.1044 and 2.1221 Pa s, with a clear dependence on temperature and SiO2 content. The atomic structure of both melt compositions was also determined at high pressure and temperature, using in situ multi-angle energy-dispersive X-ray di raction supported by ex situ microFTIR and microRaman spectroscopic measurements. Our results yield evidence that the T–T and T–O (T = Si,Al) interatomic distances of ultrabasic melts are higher than those for basaltic melts known from similar recent studies. Based on our experimental data, melilititic melts are expected to migrate at a rate ~from 2 to 57 km yr􀀀1 in the present-day or the Archaean mantle, respectively.
    Description: Published
    Description: 267
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: magma ; rheology ; viscosity ; ascent rate ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-11-08
    Description: The circulation of carbon in Earth’s interior occurs through the formation, migration, and ascent of CO2‐ bearing magmas throughout the convective mantle. Their chemical composition spans from carbonatitic to kimberlitic as a result of either temperature and pressure variations or local redox conditions at which partial melting of carbonated mantle mineral assemblages occurs. Previous experiments that focused on melting relations of synthetic CO2‐bearing mantle assemblages revealed the stability of carbonate‐silicate melts, or transitional melts, that have been generally described to mark the chemical evolution from kimberlitic to carbonatitic melts at mantle conditions. The migration of these melts upward will depend on their rheology as a function of pressure and temperature. In this study, we determined the viscosity of carbonate‐silicate liquids (~18 wt% SiO2 and 22.54 wt% CO2) using the falling‐sphere technique combined with in situ synchrotron X‐ray radiography. We performed six successful experiments at pressures between 2.4 and 5.3 GPa and temperature between 1565 °C and 2155 °C. At these conditions, the viscosity of transitional melts is between 0.02 and 0.08 Pa˙s; that is, about one order of magnitude higher than what was determined for synthetic carbonatitic melts at similar P‐T conditions, likely due to the polymerizing effect of the SiO2 component in the melt.
    Description: Published
    Description: 223-236
    Description: 1T. Struttura della Terra
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Keywords: magma, viscosity, redox, carbonate ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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