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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of peptide research and therapeutics 5 (1998), S. 269-276 
    ISSN: 1573-3904
    Keywords: metalloenzymes ; peptide-porphyrins ; solid-phase peptide-synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract New metal-tetraphenylporphyrins and Fmoc-lysine-metalloporphyrin derivatives have been used to prepare peptide-porphyrin and peptide-metalloporphyrin compounds via solid-phase peptide synthesis. A water-soluble peptide, covalently bound to a manganese(III)-porphyrin, has been used as a catalyst to promote the oxidation of ABTS by hydrogen peroxide or t-butylhydroperoxide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of peptide research and therapeutics 5 (1998), S. 269-276 
    ISSN: 1573-3904
    Keywords: metalloenzymes ; peptide-porphyrins ; solid-phase peptide-synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary New metal-tetraphenylporphyrins and Fmoc-lysine-metalloporphyrin derivatives have been used to prepare peptide-porphyrin and peptide-metalloporphyrin compounds via solid-phase peptide synthesis. A water-soluble peptide, covalently bound to a manganese(III)-porphyrin, has been used as a catalyst to promote the oxidation of ABTS by hydrogen peroxide ort-butylhydroperoxide.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
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  • 3
    Publication Date: 2021-06-22
    Description: The densely populated Po Plain, a very deep sedi- mentary basin in northern Italy, is prone to heavy shaking during earthquakes. Seismic hazard assessment must account for local variation in wave amplification. Standard ground motion prediction equations may fail to picture the complexity of strong lateral gradients in seismic response, due to sharp structural heterogeneity. For this reason, there is an increasing demand for full waveform predictions for engineering applications. Here, we present an implementation of a hybrid broadband simulation based on the method of Mai et al. (Bull Seismol Soc Am 100(6):3338–3339, 2010), to obtain complete broadband seismograms of 0.1–10 Hz. With this method, low frequency (〈1 Hz) and high frequency (1–10 Hz) seismograms are simulated separately using a deter- ministic and a stochastic method, respectively. We apply the method to four events recorded within the Po basin, with magnitude ranging from Mw = 4.4 to Mw = 5.6. The low frequency (LF) simulation is performed using SPECFEM3D on a few test sub- surface velocity models. The three-dimensional velocity model MAMBo (Molinari et al. in Bull Seismol Soc Am 105(2A):753–764, 2015)—consisting of a detailed structural description of the basin, based on extensive active-source data, embedded within a regional 3D crustal model—provided the best results for broadband simulations that most closely corresponded with the observations. It performed better than an ambient noise tomography model with more accurate S-wave velocities but less well defined layer topographies, emphasizing the importance of first order velocity discontinuities. The high frequency (HF) seis- mograms are simulated using the multiple scattering approach of Zeng et al. (J Geophys Res Solid Earth 96(B1):607–619, 1991). The scattering coefficients are obtained by performing a non linear inversion for each station to find best fitting synthetic envelopes. HF energy is then combined at 1 Hz to match the amplitude and phase spectra of the LF signal. We are able to simulate full waveforms throughout the Po Plain, of which shaking duration matches observed data for stations located in the basin. Shaking amplitudes are generally overestimated in the low frequency simulation by the MAMBo velocity model. Updating the MAMBo velocity model with more accurate S-wave velocity information of the ambient noise tomography model should improve the fit in future simulations.
    Description: Published
    Description: 2181–2198
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Ground motion ; hybrid method ; sedimentary basin ; Seismic shaking scenario ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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