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  • Inorganic Chemistry  (2)
  • 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy  (1)
  • Fluorimetrie
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  • 1
    Publication Date: 2021-09-21
    Description: Integrated Ocean Drilling Program (IODP) Expedition 317 was devoted to understanding the relative importance of global sea level (eustasy) versus local tectonic and sedimentary processes in controlling continental margin sedimentary cycles. The expedition recovered sediments from the Eocene to recent period, with a particular focus on the sequence stratigraphy of the late Miocene to recent, when global sea level change was dominated by glacioeustasy. Drilling in the Canterbury Basin, on the eastern margin of the South Island of New Zealand, takes advantage of high rates of Neogene sediment supply, which preserves a high-frequency (0.1–0.5 m.y.) record of depositional cyclicity. The Canterbury Basin provides an opportunity to study the complex interactions between processes responsible for the preserved stratigraphic record of sequences because of the proximity of an uplifting mountain chain, the Southern Alps, and strong ocean currents. Currents have locally built large, elongate sediment drifts within the prograding Neogene section. Expedition 317 did not drill into one of these elongate drifts, but currents are inferred to have strongly influenced deposition across the basin, including in locations lacking prominent mounded drifts. Upper Miocene to recent sedimentary sequences were cored in a transect of three sites on the continental shelf (landward to basinward, Sites U1353, U1354, and U1351) and one on the continental slope (Site U1352). The transect provides a stratigraphic record of depositional cycles across the shallow-water environment most directly affected by relative sea level change. Lithologic boundaries, provisionally correlative with seismic sequence boundaries, have been identified in cores from each site and provide insights into the origins of seismically resolvable sequences. This record will be used to estimate the timing and amplitude of global sea level change and to document the sedimentary processes that operate during sequence formation. Sites U1353 and U1354 provide significant, double-cored, high-recovery sections through the Holocene and late Quaternary for high-resolution study of recent glacial cycles in a continental shelf setting. Continental slope Site U1352 represents a complete section from modern slope terrigenous sediment to hard Eocene limestone, with all the associated lithologic, biostratigraphic, physical, geochemical, and microbiological transitions. The site also provides a record of ocean circulation and fronts during the last ~35 m.y. The early Oligocene (~30 Ma) Marshall Paraconformity was the deepest drilling target of Expedition 317 and is hypothesized to represent intensified current erosion or nondeposition associated with the initiation of thermohaline circulation following the separation of Australian and Antarctica. Expedition 317 set a number of scientific ocean drilling records: (1) deepest hole drilled in a single expedition and second deepest hole in the history of scientific ocean drilling (Hole U1352C, 1927 m); (2) deepest hole and second deepest hole drilled by the R/V JOIDES Resolution on a continental shelf (Hole U1351B, 1030 m; Hole U1353B, 614 m); (3) shallowest water depth for a site drilled by the JOIDES Resolution for scientific purposes (Site U1353, 84.7 m water depth); and (4) deepest sample taken by scientific ocean drilling for microbiological studies (1925 m, Site U1352). Expedition 317 supplements previous drilling of sedimentary sequences for sequence stratigraphic and sea level objectives, particularly drilling on the New Jersey margin (Ocean Drilling Program [ODP] Legs 150, 150X, 174A, and 174AX and IODP Expedition 313) and in the Bahamas (ODP Leg 166), but includes an expanded Pliocene section. Completion of at least one transect across a geographically and tectonically distinct siliciclastic margin was the necessary next step in deciphering continental margin stratigraphy. Expedition 317 also complements ODP Leg 181, which focused on drift development in more distal parts of the Eastern New Zealand Oceanic Sedimentary System (ENZOSS).
    Description: Integrated Ocean Drilling Program Management International
    Description: Published
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: restricted
    Keywords: Paleoceanography ; sea-level ; continental margin ; Canterbury Basin ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 284 (1977), S. 283-285 
    ISSN: 1618-2650
    Keywords: Best. von Benzo(a)pyren in Luft ; Fluorimetrie ; DC-Trennung, H2SO4-Lösung
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary The potentiality of the method for the determination of benzo(a)pyrene (BaP) in airborne particulates, based on the fluorescence measurements in H2SO4, was investigated. Stability of the BaP fluorescence in H2SO4, isolation of the BaP fraction by thin-layer chromatography and the effect of quenchers on the fluorescence intensity of BaP were studied and the results are discussed. The relative standard deviation of the method was determined to be 2.9 and 5.9% for BaP levels of 265 and 68 ng, respectively.
    Notes: Zusammenfassung Die Möglichkeiten der Benzo(a)pyrenbestimmung durch Fluorescenzmessung in schwefelsaurer Lösung wurden untersucht. Die Stabilität der Fluorescenz, die Isolierung der Benzo(a)pyrenfraktion durch Dünnschicht-Chromatographie sowie der Einfluß fluorescenzlöschender Substanzen wurden geprüft und die Ergebnisse diskutiert. Die relative Standardabweichung des Verfahrens beträgt 2,9 und 5,9% für Benzo(a)pyrenmengen von 265 bzw. 68 ng.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 121 (1988), S. 1729-1738 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Novel Cluster Frameworks from the Reactions of the Unsaturated Clusters Fe4(CO)11(μ4-PR)2 with AlkynesThe unsaturated clusters Fe4(CO)11(μ4-PR)2 (1-3, R = Ph, p-Tol, t-Bu) react with terminal alkynes primarily by insertion of the alkyne between one phosphorus and two iron atoms. The structure analysis of Fe4(CO)11(μ4-PTol)[μ4-P(Tol)-CMeCH] and NMR studies in solution show that the insertion products exist as two isomers, which differ by the orientation of the alkyne (P—CR—CH—Fe/P—CH—CR—Fe), and whose interconversion in solution can be catalyzed by bases. Starting from 3, additionally and preferentially alkyne-containing clusters are formed with CO elimination, which contain a novel Fe4P2C2 framework that can be derived from a pentagonal bipyramid with an equatorial Fe2PC2 unit as evidenced by the structure determination of Fe4(CO)9(μ3-P-tBu)[μ4-P-(tBu)CHCMe]. The primary alkyne-insertion products are easily induced by an excess of donor ligands [CO, P(OM)3, tBuNC] or by iodine oxidation to eliminate one ironcarbonyl unit and form the clusters Fe4(CO)9(μ3-P-tBu)[μ4-P-(tBu)CHCMe] and substituted derivatives thereof. For these the structure analysis of the (PhPCHCMePPh) compound proves the PCCP sequence and a side-on coordination of the C2 unit to one iron atom. The degradation with P(OMe)3 and tBuNC produces as intermediates the substitution derivatives Fe4(CO)10L(μ4-PPh)-[μ4-P(Ph)CRCH], which also exist as two isomers with different orientation of the CR—CH unit.
    Notes: Die ungesättigten Cluster Fe4(CO)11(μ4-PR)2 (1-3, R = Ph, p-Tol, t-Bu) reagieren mit terminalen Alkinen primär unter Insertion des Alkins zwischen einem Phosphor- und zwei Eisen-Atomen. Die Strukturanalyse von Fe4(CO)11(μ4-PTol)[μ4-P(Tol)-CMeCH] und NMR-Studien in Lösung zeigen, daß die Insertionsprodukte in Form von zwei Isomeren vorliegen, die sich durch die Orientierung des Alkins (P—CR—CH—Fe/P—CH—CR—Fe) unterscheiden und deren gegenseitige Umwandlung in Lösung sich durch Basen katalysieren läßt. Aus 3 entstehen zusätzlich und bevorzugt unter CO-Abspaltung alkinhaltige Cluster mit einem neuartigen Fe4P2C2-Gerüst, das sich von einer pentagonalen Bipyramide mit äquatorialer Fe2PC2-Einheit ableiten läßt, wie die Strukturanalyse von Fe4(CO)9(μ3-P-tBu)[μ4-P-(tBu)CHCMe] belegt. Die primären Alkin-Insertionsprodukte werden durch überschüssige Donorliganden [CO, P(OM)3, tBuNC] und durch Oxidation mit Iod leicht unter Abspaltung einer Eisencarbonyl-Einheit zu den Clustern Fe3(CO)9[μ3-μ3-P(R)-CHCR′PR] bzw. substituierten Derivaten davon abgebaut. Für diese beweist die Strukturanalyse der (PhPCHCMePPh)-Verbindung die PCCP-Verknüpfung und eine Seitwärtskoordination der C2-Einheit an ein Eisen-Atom. Der Abbau verläft mit P(OM)3 und tBuNC über die Substitutionsprodukte Fe4(CO)10L(μ4—PPh)-[μ-P(Ph)CRCH], die ebenfalls in Form von zwei Isomeren mit unterschiedlicher CR—CH-Orientierung vorkommen.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 9 (1876), S. 1554-1557 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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