ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (39)
Collection
Years
  • 1
    Publication Date: 2021-06-15
    Description: Twenty-two gas samples were collected in August 2012 in the area of Amik basin (Turkey). Two samples were collected from gas seeps, one was a bubbling gas in a thermal spring, while the remaining were dissolved gases from cold and thermal groundwaters (T 16-43 °C). All gases were analysed for their chemical composition (He, H2, O2, N2, CH4 and CO2) and for their He isotopic composition. Dissolved gases were also analysed for the carbon isotopic composition of the total dissolved carbon (TDC), while free gases also for their higher hydrocarbon (C1 – C5) content and for D of H2 and CH4, 13C of CH4 Basing on their chemical composition, the gases can be roughly subdivided in three groups. Most of the dissolved gases (16) belonging to the first group were collected from springs or shallow wells (〈 150 m depth). All these samples contain mainly atmospheric gasses with very limited H2 (〈 80 ppm) and CH4 (1 – 2700 ppm) contents and minor concentrations of CO2 (0.5 – 11.2 %). The isotopic composition of TDC evidences an almost organic contribution. The only exception is represented by the CO2-richest sample where a small but significant mantle contribution is found. Such contribution can also be evidenced in its 3He rich isotopic composition. Further three samples of this group evidence a small mantle contribution. These samples were collected in the northern part of the basin along the main tectonic structures delimiting the basin and close to areas with quaternary volcanic activity. A second group is composed by two dissolved gases collected from deep boreholes (〉 1200 m depth). Their composition is typical of hydrocarbon reservoirs being very rich in CH4 (〉 78 %) and N2 (〉 13%). Also the water composition is typical of saline connate waters (Cl- and B-rich, SO4-poor). C-isotopic composition of methane ( 13C -65% ) points to a biogenic origin while He-isotopic composition indicates a prevailing crustal signature for one (R/Ra 0.16) of the sites and small mantle contribution for the other (R/Ra 0.98). To the last group belong four gas samples taken at two sites within the ophiolitic basement that crops out west of the basin. These gases have the characteristic composition of gas generated by low temperature serpentinisation processes with high hydrogen (37 – 50 %) and methane (10 – 61 %) concentrations. While all gases show an almost identical D-H2 of -750h those of one of the two sites display an isotopic composition of methane ( 13C -5h D -105% ) and a C1/[C2+C3] ( 100) ratio typical of abiogenic hydrocarbons and mantle-type helium (R/Ra: 1.33), while those of the other site evidence a contribution of a crustal (thermogenic) component ( 13C-CH4 -30h D -325h C1/[C2+C3] 3000). Such crustal contribution is also supported by higher N2 contents (40% instead of 2%) and lower He-isotopic composition (R/Ra 0.07). The preliminary results highlight contributions of mantle-derived volatiles to the fluids vented along the Amik Basin. The main tectonic structure of the area, the Death Sea Fault, and other parallel structures crossing the basin seem to be the responsible for deep-originated volatiles drainage towards shallow levels.
    Description: Submitted
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2021-07-14
    Description: The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y–Ho and Zr–Hf (twin pairs) have a different behaviour in strong acidic waterswith respect to the water with pH near-neutral. Yttrium and Ho behave as Zr and Hf in waters with pH near neutral-to-neutral, showing superchondritic ratios. The twin pairs showed to be sensitive to the co-precipitation and/or adsorption onto the surface of authigenic particulate (Fe-, Al-oxyhydroxides), suggesting an enhanced scavenging of Ho and Hf with respect to Y and Zr, leading to superchondritic values. In acidic waters, a different behaviour of twin pairs occurs with chondritic Y/Ho ratios and sub-chondritic Zr/Hf ratios. For the first time, Zr and Hf were investigated in natural acidic fluids to understand the behaviour of these elements in extreme acidic conditions and different major anion chemistry. Zr/Hf molar ratio changes from 4.75 to 49.29 in water with pH b 3.6. In strong acidic waters the fractionation of Zr and Hf was recognized as function of major anion contents (Cl and SO4), suggesting the formation of complexes leading to sub-chondritic Zr/Hf molar ratios.
    Description: Published
    Description: 125–133
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Zirconium ; Hafnium ; Rare earth elements ; Ionic complexes ; Acidic waters ; Fe–Al oxyhydroxides ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey on the fluids released by the volcanic/geothermal system of Methana was undertaken. Characterization of the gases was made on the basis of the chemical and isotopic (He and C) analysis of 14 samples. CO2 soil gas concentration and fluxes were measured on the whole peninsula at more than 100 sampling sites. 31 samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of aquifers. Anomalies referable to the geothermal system, besides at known thermal manifesta-tions, were also recognized at some anomalous degassing soil site and in some cold groundwater. These anomalies were always spatially correlated to the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated in about 0.2 kg s-1. Although this value is low compared to other volcanic systems, anomalous CO2 degassing at Methana may pose gas hazard problems. Such volcanic risk, although restricted to limited areas, cannot be neglected and further studies have to be undertaken for its better assessment
    Description: Published
    Description: 712-722
    Description: N/A or not JCR
    Description: open
    Keywords: soil gases ; CO2 fluxes ; gas hazard ; groundwater chemistry ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2017-04-04
    Description: A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system of Methana was undertaken collecting 59 natural water samples during the period 2004-2007. Methana is a peninsula whose climatology and hydrology can be compared to the nearby small islands of the Aegean Sea. Similarly the chemical and isotopic composition of its water is dominated by the mixing of seawater with meteoric water. But the simple mixing trend is modified by water-rock interaction processes, enhanced by the dissolution of endogenous CO2, leading to strong enrichments in Alkalinity, Calcium, Barium, Iron and Manganese.
    Description: Published
    Description: Athens, Greece
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Methana ; thermal waters ; groundwaters ; hydrochemistry ; stable isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2017-04-04
    Description: Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their Cl-, Br- and F- contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7600 inhabitants. The contents of Cl- and Br-, ranging between 5.53 and 1302 mg/l and between 〈 0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only 3 exceeding the maximum admissible concentration of 1.5 mg/l) generally correlated either with the presence in the area of crystalline (volcanic or metamorphic) or evaporitic rocks or with contamination from hydrothermal activity. Apart from these limited cases of exceeding F- levels, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products.
    Description: Published
    Description: 303-313
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: drinking water quality ; fluoride ; bromide ; chloride ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2017-04-04
    Description: Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their chloride, bromide, fluoride, sulphate and nitrate contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7600 inhabitants. The contents of chloride and bromide, ranging between 5.53 and 1302 mg/l and between 〈 0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The nitrate concentrations were in the range 0.05 – 296 mg/l. Of the analysed samples about 4.4% exceeded the maximum admissible concentration (MAC) of 50 mg/l. The highest values were always measured in areas of intense agricultural exploitation. The sulphate concentrations varied between 6.03 and 516 mg/l, exceeding in about 1.2% of the cases the guideline level of 250 mg/l. The highest values were always related either to evaporitic rock dissolution or to seawater intrusion. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only 3 exceeding the MAC of 1.5 mg/l) generally attributed either to the leaching of crystalline (volcanic or metamorphic) or evaporitic rocks or to contamination from a hydrothermal component. Apart from these limited cases of exceeding of MACs, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products. Also nitrate concentrations, although sometimes exceeding MAC, display generally level well suited for human consumption, the population-weighted average being about 16 mg/l for the whole Sicily. As regards geographic distribution, the best water quality was found in areas with the most humid climate and with huge aquifers in the north-eastern part of the island. On the contrary especially along the southern coasts of Sicily, arid conditions and the widespread presence of impermeable lithologies, sometimes forces the use of low quality water resources. But it is also worth to note that bad management often exacerbates water quality and quantity problems in these areas.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Sicily ; drinking water ; fluoride ; bromide ; chloride ; sulphate ; nitrate ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2017-04-04
    Description: The Florina basin developed in the Pelagonian Zone, the westernmost zone of the Internal Hellenides, in response to NE–SW extension in the Late Miocene and to a subsequent Pleistocene episode of NW–SE extension. Continuous sedimentation resulted in the accumulation of a 560 m thick succession of Late Miocene to Early Pleistocene lake sediments with intercalated lignites and alluvial deposits. The presence of intercalated volcanic ash beds of Pliocene age evidences volcanic activity related to the exstensional tectonics. Groundwaters in the central part of the Florina plain display high levels of dissolved gases, which often separate in a free gas phase. Their composition is dominated by carbon dioxide, which accounts for 85-99% of these gases. Apart from small amounts of atmospheric gases, minor components are CH4 (0.05-0.4%) and He (3-30 ppm). Carbon isotopic composition ranging from –1.6 to 0.3‰ (vs. VPDB) testifies for a deep (magmatic-hydrothermal) origin of CO2 and also He isotopic composition (0.24-0.55 R/Ra) reveals a small (3.5-8.4%) but significant mantle contribution. Furthermore the water composition of a deep well (Mesochori) shows important contribution from a hydrothermal component, displaying very high Li and B contents and a clear isotopic shift on a δD-δ18O diagram. Geothermometric estimates of the deep reservoir are in the range 150-180 °C. The uprise of mantle gases is related to the main tectonic structures, which probably allowed also magma intrusion episodes whose heat flow sustain the deep hydrothermal system. Because of the huge input of CO2, the shallow groundwaters of the studied area become acidic and consequently strongly aggressive with respect to the host rocks. At the sampling point many waters display pH values down to 5.5, being generally under the lower limit for drinking waters. Intense rock leaching results in metal release to the solution and enhanced metal fluxes in the aqueous system. As such, magmatic-hydrothermal CO2 input produces a “natural pollution” of the aquifer, where maximum admissible concentrations (MAC) fixed by European Union for drinking waters are exceeded at least for Ni, Mn and Fe in most of the analysed samples. Measured values reach respectively up to 30, 1700 and 55000 µg/l (MACs 20, 50 and 200 µg/l). This natural contamination combines with the pollution due to agricultural practices in the Florina plain, which is responsible for elevated nitrate contents (up to 90 mg/l) often exceeding maximum admissible concentration (50 mg/l). The interaction of natural and anthropogenic contamination of the shallow groundwater resources in the Florina area leads to serious water quality issues.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Greece ; Florina ; groundwater quality ; carbon dioxide ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2017-04-04
    Description: New chemical and isotope data for 74 groundwater samples from the southwestern slopes of Mt. Etna are presented. The processes responsible for the considerable chemical heterogeneity displayed by groundwaters were identified through factor analysis and by the use of mass balance calculations. A general hydrogeochemical model, concerning the interactions between the shallow volcanic aquifer, deep magmaderived fluids and the underlain sedimentary sequence, is also provided.
    Description: Published
    Description: 125-145
    Description: partially_open
    Keywords: Mt.Etna ; Hydrogeochemistry ; multivariate statistical analysis ; mass balance calculation ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
    Format: 535 bytes
    Format: 1646620 bytes
    Format: text/html
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...