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  • 1
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    Evidence that the reactivity of the martian soil is due to superoxide ions (2000)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2000-09-16
    Description: The Viking Landers were unable to detect evidence of life on Mars but, instead, found a chemically reactive soil capable of decomposing organic molecules. This reactivity was attributed to the presence of one or more as-yet-unidentified inorganic superoxides or peroxides in the martian soil. Using electron paramagnetic resonance spectroscopy, we show that superoxide radical ions (O2-) form directly on Mars-analog mineral surfaces exposed to ultraviolet radiation under a simulated martian atmosphere. These oxygen radicals can explain the reactive nature of the soil and the apparent absence of organic material at the martian surface.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Yen, A S -- Kim, S S -- Hecht, M H -- Frant, M S -- Murray, B -- New York, N.Y. -- Science. 2000 Sep 15;289(5486):1909-12.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA. Albert.Yen@jpl.nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/10988066" target="_blank"〉PubMed〈/a〉
    Keywords: Aluminum Silicates/chemistry ; Electron Spin Resonance Spectroscopy ; Exobiology ; Extraterrestrial Environment ; Ions ; *Mars ; Oxygen ; Potassium Compounds/chemistry ; *Soil ; *Superoxides/analysis/chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    Detection of silica-rich deposits on Mars (2008)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2008-05-24
    Description: Mineral deposits on the martian surface can elucidate ancient environmental conditions on the planet. Opaline silica deposits (as much as 91 weight percent SiO2) have been found in association with volcanic materials by the Mars rover Spirit. The deposits are present both as light-toned soils and as bedrock. We interpret these materials to have formed under hydrothermal conditions and therefore to be strong indicators of a former aqueous environment. This discovery is important for understanding the past habitability of Mars because hydrothermal environments on Earth support thriving microbial ecosystems.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Squyres, S W -- Arvidson, R E -- Ruff, S -- Gellert, R -- Morris, R V -- Ming, D W -- Crumpler, L -- Farmer, J D -- Marais, D J Des -- Yen, A -- McLennan, S M -- Calvin, W -- Bell, J F 3rd -- Clark, B C -- Wang, A -- McCoy, T J -- Schmidt, M E -- de Souza, P A Jr -- New York, N.Y. -- Science. 2008 May 23;320(5879):1063-7. doi: 10.1126/science.1155429.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Astronomy, Space Sciences Building, Cornell University, Ithaca, NY 14853, USA. squyres@astro.cornell.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18497295" target="_blank"〉PubMed〈/a〉
    Keywords: Extraterrestrial Environment ; Hot Temperature ; Hydrogen-Ion Concentration ; *Mars ; *Silicon Dioxide ; Spacecraft ; *Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    Exploration of Victoria crater by the Mars rover Opportunity (2009)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2009-05-23
    Description: The Mars rover Opportunity has explored Victoria crater, an approximately 750-meter eroded impact crater formed in sulfate-rich sedimentary rocks. Impact-related stratigraphy is preserved in the crater walls, and meteoritic debris is present near the crater rim. The size of hematite-rich concretions decreases up-section, documenting variation in the intensity of groundwater processes. Layering in the crater walls preserves evidence of ancient wind-blown dunes. Compositional variations with depth mimic those approximately 6 kilometers to the north and demonstrate that water-induced alteration at Meridiani Planum was regional in scope.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Squyres, S W -- Knoll, A H -- Arvidson, R E -- Ashley, J W -- Bell, J F 3rd -- Calvin, W M -- Christensen, P R -- Clark, B C -- Cohen, B A -- de Souza, P A Jr -- Edgar, L -- Farrand, W H -- Fleischer, I -- Gellert, R -- Golombek, M P -- Grant, J -- Grotzinger, J -- Hayes, A -- Herkenhoff, K E -- Johnson, J R -- Jolliff, B -- Klingelhofer, G -- Knudson, A -- Li, R -- McCoy, T J -- McLennan, S M -- Ming, D W -- Mittlefehldt, D W -- Morris, R V -- Rice, J W Jr -- Schroder, C -- Sullivan, R J -- Yen, A -- Yingst, R A -- New York, N.Y. -- Science. 2009 May 22;324(5930):1058-61. doi: 10.1126/science.1170355.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Astronomy, Space Sciences Building, Cornell University, Ithaca, NY 14853, USA. squyres@astro.cornell.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/19461001" target="_blank"〉PubMed〈/a〉
    Keywords: Extraterrestrial Environment ; Ferric Compounds ; *Mars ; Spacecraft ; Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
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    Identification of carbonate-rich outcrops on Mars by the Spirit rover (2010)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2010-06-05
    Description: Decades of speculation about a warmer, wetter Mars climate in the planet's first billion years postulate a denser CO2-rich atmosphere than at present. Such an atmosphere should have led to the formation of outcrops rich in carbonate minerals, for which evidence has been sparse. Using the Mars Exploration Rover Spirit, we have now identified outcrops rich in magnesium-iron carbonate (16 to 34 weight percent) in the Columbia Hills of Gusev crater. Its composition approximates the average composition of the carbonate globules in martian meteorite ALH 84001. The Gusev carbonate probably precipitated from carbonate-bearing solutions under hydrothermal conditions at near-neutral pH in association with volcanic activity during the Noachian era.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Morris, Richard V -- Ruff, Steven W -- Gellert, Ralf -- Ming, Douglas W -- Arvidson, Raymond E -- Clark, Benton C -- Golden, D C -- Siebach, Kirsten -- Klingelhofer, Gostar -- Schroder, Christian -- Fleischer, Iris -- Yen, Albert S -- Squyres, Steven W -- New York, N.Y. -- Science. 2010 Jul 23;329(5990):421-4. doi: 10.1126/science.1189667. Epub 2010 Jun 3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉NASA Johnson Space Center, Houston, TX 77058, USA. richard.v.morris@nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/20522738" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere ; Carbon Dioxide ; *Carbonates/chemistry ; Climate ; Extraterrestrial Environment ; Ferrous Compounds ; Magnesium ; *Mars ; Meteoroids ; Spacecraft ; Temperature ; *Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
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    Mineralogy at Gusev Crater from the Mossbauer spectrometer on the Spirit Rover (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-08-07
    Description: Mossbauer spectra measured on Mars by the Spirit rover during the primary mission are characterized by two ferrous iron doublets (olivine and probably pyroxene) and a ferric iron doublet (tentatively associated to nanophase ferric iron oxide). Two sextets resulting from nonstoichiometric magnetite are also present, except for a coating on the rock Mazatzal, where a hematite-like sextet is present. Greater proportions of ferric-bearing phases are associated with undisturbed soils and rock surfaces as compared to fresh rock surfaces exposed by grinding. The ubiquitous presence of olivine in soil suggests that physical rather than chemical weathering processes currently dominate at Gusev crater.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Morris, R V -- Klingelhofer, G -- Bernhardt, B -- Schroder, C -- Rodionov, D S -- De Souza, P A Jr -- Yen, A -- Gellert, R -- Evlanov, E N -- Foh, J -- Kankeleit, E -- Gutlich, P -- Ming, D W -- Renz, F -- Wdowiak, T -- Squyres, S W -- Arvidson, R E -- New York, N.Y. -- Science. 2004 Aug 6;305(5685):833-6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉NASA Johnson Space Center, Houston, TX, USA. richard.v.morris@nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15297666" target="_blank"〉PubMed〈/a〉
    Keywords: Extraterrestrial Environment ; Ferric Compounds ; Ferrosoferric Oxide ; Geologic Sediments ; Iron ; *Iron Compounds ; Magnesium Compounds ; *Mars ; *Minerals ; Oxides ; Silicates ; Spectroscopy, Mossbauer
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    Chemistry of rocks and soils at Meridiani Planum from the Alpha Particle X-ray Spectrometer (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-12-04
    Description: The Alpha Particle X-ray Spectrometer on the Opportunity rover determined major and minor elements of soils and rocks in Meridiani Planum. Chemical compositions differentiate between basaltic rocks, evaporite-rich rocks, basaltic soils, and hematite-rich soils. Although soils are compositionally similar to those at previous landing sites, differences in iron and some minor element concentrations signify the addition of local components. Rocky outcrops are rich in sulfur and variably enriched in bromine relative to chlorine. The interaction with water in the past is indicated by the chemical features in rocks and soils at this site.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rieder, R -- Gellert, R -- Anderson, R C -- Bruckner, J -- Clark, B C -- Dreibus, G -- Economou, T -- Klingelhofer, G -- Lugmair, G W -- Ming, D W -- Squyres, S W -- d'Uston, C -- Wanke, H -- Yen, A -- Zipfel, J -- New York, N.Y. -- Science. 2004 Dec 3;306(5702):1746-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Max-Planck-Institut fur Chemie, J. J. Becher-Weg 27, D-55128 Mainz, Germany. rieder@mpch-mainz.mpg.de〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15576611" target="_blank"〉PubMed〈/a〉
    Keywords: Alpha Particles ; Bromine ; Chlorine ; Elements ; Extraterrestrial Environment ; Ferric Compounds ; Geologic Sediments ; Iron ; Magnesium ; *Mars ; Minerals ; Silicates ; Spacecraft ; Spectrometry, X-Ray Emission ; Sulfates ; Sulfur ; Water
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    Jarosite and hematite at Meridiani Planum from Opportunity's Mossbauer Spectrometer (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-12-04
    Description: Mossbauer spectra measured by the Opportunity rover revealed four mineralogical components in Meridiani Planum at Eagle crater: jarosite- and hematite-rich outcrop, hematite-rich soil, olivine-bearing basaltic soil, and a pyroxene-bearing basaltic rock (Bounce rock). Spherules, interpreted to be concretions, are hematite-rich and dispersed throughout the outcrop. Hematitic soils both within and outside Eagle crater are dominated by spherules and their fragments. Olivine-bearing basaltic soil is present throughout the region. Bounce rock is probably an impact erratic. Because jarosite is a hydroxide sulfate mineral, its presence at Meridiani Planum is mineralogical evidence for aqueous processes on Mars, probably under acid-sulfate conditions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Klingelhofer, G -- Morris, R V -- Bernhardt, B -- Schroder, C -- Rodionov, D S -- de Souza, P A Jr -- Yen, A -- Gellert, R -- Evlanov, E N -- Zubkov, B -- Foh, J -- Bonnes, U -- Kankeleit, E -- Gutlich, P -- Ming, D W -- Renz, F -- Wdowiak, T -- Squyres, S W -- Arvidson, R E -- New York, N.Y. -- Science. 2004 Dec 3;306(5702):1740-5.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institut fur Anorganische und Analytische Chemie, Johannes Gutenberg-Universitat, Staudinger Weg 9, D-55128 Mainz, Germany. phil.christensen@asu.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15576610" target="_blank"〉PubMed〈/a〉
    Keywords: Extraterrestrial Environment ; *Ferric Compounds ; Geologic Sediments ; Iron Compounds ; Magnesium Compounds ; *Mars ; Minerals ; Silicates ; Spacecraft ; Spectroscopy, Mossbauer ; *Sulfates ; Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 8
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    Magnetic properties experiments on the Mars exploration Rover Spirit at Gusev Crater (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-08-07
    Description: The magnetic properties experiments are designed to help identify the magnetic minerals in the dust and rocks on Mars-and to determine whether liquid water was involved in the formation and alteration of these magnetic minerals. Almost all of the dust particles suspended in the martian atmosphere must contain ferrimagnetic minerals (such as maghemite or magnetite) in an amount of approximately 2% by weight. The most magnetic fraction of the dust appears darker than the average dust. Magnetite was detected in the first two rocks ground by Spirit.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Bertelsen, P -- Goetz, W -- Madsen, M B -- Kinch, K M -- Hviid, S F -- Knudsen, J M -- Gunnlaugsson, H P -- Merrison, J -- Nornberg, P -- Squyres, S W -- Bell, J F 3rd -- Herkenhoff, K E -- Gorevan, S -- Yen, A S -- Myrick, T -- Klingelhofer, G -- Rieder, R -- Gellert, R -- New York, N.Y. -- Science. 2004 Aug 6;305(5685):827-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Center for Planetary Science, Danish Space Research Institute and Niels Bohr Institute for Astronomy, Physics and Geophysics, University of Copenhagen, DK-2100 Copenhagen, Denmark. preben@fys.ku.dk〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15297664" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere ; Extraterrestrial Environment ; Ferrosoferric Oxide ; Geologic Sediments ; Iron ; *Magnetics ; *Mars ; *Minerals ; Oxides ; Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 9
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    Basaltic rocks analyzed by the Spirit Rover in Gusev Crater (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-08-07
    Description: The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini-Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain 〈/=25% megacrysts. Chemical analyses of rocks by the Alpha Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. Mossbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. These basalts extend the known range of rock compositions composing the martian crust.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉McSween, H Y -- Arvidson, R E -- Bell, J F 3rd -- Blaney, D -- Cabrol, N A -- Christensen, P R -- Clark, B C -- Crisp, J A -- Crumpler, L S -- Des Marais, D J -- Farmer, J D -- Gellert, R -- Ghosh, A -- Gorevan, S -- Graff, T -- Grant, J -- Haskin, L A -- Herkenhoff, K E -- Johnson, J R -- Jolliff, B L -- Klingelhoefer, G -- Knudson, A T -- McLennan, S -- Milam, K A -- Moersch, J E -- Morris, R V -- Rieder, R -- Ruff, S W -- De Souza, P A Jr -- Squyres, S W -- Wanke, H -- Wang, A -- Wyatt, M B -- Yen, A -- Zipfel, J -- New York, N.Y. -- Science. 2004 Aug 6;305(5685):842-5.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Earth and Planetary Sciences, University of Tennessee, Knoxville, TN 37996-1410, USA. mcsween@utk.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15297668" target="_blank"〉PubMed〈/a〉
    Keywords: Extraterrestrial Environment ; Geologic Sediments ; Iron Compounds ; Magnesium Compounds ; *Mars ; *Minerals ; Oxides ; *Silicates ; Spectroscopy, Mossbauer ; Spectrum Analysis ; Water
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    The Opportunity Rover's Athena science investigation at Meridiani Planum, Mars (2004)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 2004-12-04
    Description: The Mars Exploration Rover Opportunity has investigated the landing site in Eagle crater and the nearby plains within Meridiani Planum. The soils consist of fine-grained basaltic sand and a surface lag of hematite-rich spherules, spherule fragments, and other granules. Wind ripples are common. Underlying the thin soil layer, and exposed within small impact craters and troughs, are flat-lying sedimentary rocks. These rocks are finely laminated, are rich in sulfur, and contain abundant sulfate salts. Small-scale cross-lamination in some locations provides evidence for deposition in flowing liquid water. We interpret the rocks to be a mixture of chemical and siliciclastic sediments formed by episodic inundation by shallow surface water, followed by evaporation, exposure, and desiccation. Hematite-rich spherules are embedded in the rock and eroding from them. We interpret these spherules to be concretions formed by postdepositional diagenesis, again involving liquid water.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Squyres, S W -- Arvidson, R E -- Bell, J F 3rd -- Bruckner, J -- Cabrol, N A -- Calvin, W -- Carr, M H -- Christensen, P R -- Clark, B C -- Crumpler, L -- Marais, D J Des -- d'Uston, C -- Economou, T -- Farmer, J -- Farrand, W -- Folkner, W -- Golombek, M -- Gorevan, S -- Grant, J A -- Greeley, R -- Grotzinger, J -- Haskin, L -- Herkenhoff, K E -- Hviid, S -- Johnson, J -- Klingelhofer, G -- Knoll, A H -- Landis, G -- Lemmon, M -- Li, R -- Madsen, M B -- Malin, M C -- McLennan, S M -- McSween, H Y -- Ming, D W -- Moersch, J -- Morris, R V -- Parker, T -- Rice, J W Jr -- Richter, L -- Rieder, R -- Sims, M -- Smith, M -- Smith, P -- Soderblom, L A -- Sullivan, R -- Wanke, H -- Wdowiak, T -- Wolff, M -- Yen, A -- New York, N.Y. -- Science. 2004 Dec 3;306(5702):1698-703.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Astronomy, Space Sciences Building, Cornell University, Ithaca, NY 14853, USA. squyres@astro.cornell.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/15576602" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere ; Evolution, Planetary ; Extraterrestrial Environment ; Ferric Compounds ; Geologic Sediments ; *Mars ; Minerals ; Silicates ; Spacecraft ; Water ; Wind
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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