ansa-titanocenes and ansa-zirconocenes
Springer Online Journal Archives 1860-2000
Chemistry and Pharmacology
Abstract A series of methyl and allyl derivatives of ansa-titano- and ansa-zirconocenes with isopropylidene or dimethylsilyl bridging groups were synthesized. A dinuclear complex, [Me2C(C5H4)2]2Ti2O2, resulting from the thermal decomposition of the corresponding dimethyl derivative of ansa-titanocene in the air, was characterized by X-ray diffraction analysis.
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