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  • di-sodium cobalt vanadium hepta-fluoride  (1)
  • disodium metal(II) vanadium(III) heptafluorides  (1)
  • 1995-1999  (2)
  • 1
    ISSN: 0044-2313
    Keywords: Weberite structure ; structure determination ; di-sodium iron vanadium hepta-fluoride ; di-sodium iron chromium hepta-fluoride ; di-sodium cobalt vanadium hepta-fluoride ; disodium cobalt chromium hepta-fluoride ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure Determinations of Four Monoclinic Weberites Na2MIIMIIIF7 (MII = Fe, Co; MIII = V, Cr)By solid state reaction of the binary fluorides single crystals of the following weberites were prepared and their monoclinic structure (space group C2/c, Z = 16) determined by X-ray methods: Na2FeVF7 (a = 1 271.0(3), b = 742.9(1), c = 2 471.6(5) pm, β = 100.03(3)°; R1 = 0.043 (1 545 Reflexe); Fe—F = 203.8, V—F = 193.0 pm); Na2FeCrF7 (a = 1 262.5(3), b = 739.1(1), c = 2 460.5(5) pm, β = 99.93(3)°; R1 = 0.029 (2 340); Fe—F = 203.6, Cr—F = 190.5 pm); Na2CoVF7 (a = 1 270.3(5), b = 739.1(3), c = 2 465.1(10) pm, β = 100.02(3)°; R1 = 0.028 (2 250); Co—F = 201.6, V—F = 193.6 pm); Na2CoCrF7 (a = 1 257.8(3), b = 733.5(1), c = 2 441.5(5) pm, β = 99.64(3)°; R1 = 0.030 (2 227); Co—F = 201.2, Cr—F = 190.2 pm). Concerning the above average distances within the distorted [MF6] octahedra and the shape of [NaF8] coordination details are given and discussed.
    Notes: Durch Festkörperreaktion der binären Fluoride wurden Einkristalle der folgenden Weberite dargestellt und röntgenographisch deren monokline Struktur bestimmt (Raumgruppe C2/c, Z = 16): Na2FeVF7 (a = 1 271,0(3), b = 742,9(1), c = 2 471,6(5) pm, β = 100,03(3)°; R1 = 0,043 (1 545 Reflexe); Fe—F = 203,8, V—F = 193,0 pm); Na2FeCrF7 (a = 1 262,5(3), b = 739,1(1), c = 2 460,5(5) pm, β = 99,93(3)°; R1 = 0,029 (2 340); Fe—F = 203,6, Cr—F = 190,5 pm); Na2CoVF7 (a = 1 270,3(5), b = 739,1(3), c = 2 465,1(10) pm, β = 100,02(3)°; R1 = 0,028 (2 250); Co—F = 201,6, V—F = 193,6 pm); Na2CoCrF7 (a = 1 257,8(3), b = 733,5(1), c = 2 441,5(5) pm, β = 99,64(3)°; R1 = 0,030 (2 227); Co—F = 201,2, Cr—F = 190,2 pm). Zu den genannten mittleren Abständen in den verzerrten [MF6]-Oktaedern und zur Form der [NaF8]-Koordination werden Einzelheiten mitgeteilt und diskutiert.
    Additional Material: 3 Ill.
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  • 2
    ISSN: 0044-2313
    Keywords: Structure determination ; vanadium weberites ; disodium metal(II) vanadium(III) heptafluorides ; sodium tetrafluoro-vanadate(III) ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structures of the Vanadium Weberites Na2MIIVIIIF7 (MII = Mn, Ni, Cu) and of NaVF4At single crystals of the vanadium(III) compounds NaVF4 (a = 790.1, b = 531.7, c = 754.0 pm, β = 101.7°; P21/c, Z = 4), Na2NiVF7 (a = 726.0, b = 1031.9, c = 744.6 pm; Imma, Z = 4) and Na2CuVF7 (a = 717.6, b = 1043.5, c = 754.6 pm; Pmnb, Z = 4) X-ray structure determinations were performed, at Na2MnVF7 (a = 746.7, c = 1821.6 pm; P3221, Z = 6) a new refinement. NaVF4 crystallizes in the layer structure type of NaNbO2F2. The fluorides Na2MIIVF7 represent new orthorhombic (MII = Ni; Cu) resp. trigonal (MII = Mn) weberites. The average distances within the [VF6] octahedra of the four compounds are in good agreement with each other and with data of related fluorides (V—F: 193.3 pm). The differences between mean bond lengths of terminal and bridging F ligands are 5% in NaVF4, but less than 1% in the weberites. Details and data for comparison are discussed.
    Notes: An Einkristallen der Vanadium(III)-Verbindungen NaVF4 (a = 790,1, b = 531,7, c = 754,0 pm, β = 101,7°; P21/c, Z = 4), Na2NiVF7 (a = 726,0, b = 1031,9, c = 744,6 pm; Imma, Z = 4) und Na2CuVF7 (a = 717,6, b = 1043,5, c = 754,6 pm; Pmnb, Z = 4) wurden Röntgenstrukturbestimmungen durchgeführt, an Na2MnVF7 (a = 746,7, c = 1821,6 pm; P3221, Z = 6) eine neue Verfeinerung. NaVF4 kristallisiert in der Schichtstruktur des NaNbO2F2-Typs. Die Fluoride Na2MIIVF7 sind neue orthorhombische (MII = Ni; Cu) bzw. trigonale (MII = Mn) Weberit-Vertreter. Die mittleren Abstände in den [VF6]-Oktaedern der vier Verbindungen stimmen gut miteinander und mit Daten in verwandten Fluoriden überein (V—F: 193,3 pm). Die Unterschiede zwischen den mittleren Abständen terminaler und verbrückender F-Liganden betragen in NaVF4 5%, in den Weberiten aber weniger als 1%. Einzelheiten und Vergleichsdaten werden diskutiert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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