All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

  • 1
    ISSN: 0044-2313
    Keywords: Dimethyl(methanesulfinyl)sulfonium-Hexafluorometallates ; Vibrational-, NMR-, Mass-Spectra ; Crystal Structure of CH3S(O)Cl ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dimethyl(methanesulfinyl)sulfonium Hexafluorometallates (CH3)2SS(O)CH3+MF6- (M = As, Sb) and the Crystal Structure of Methanesulfinylchloride CH3S(O)Cl [1]The preparation of dimethyl(methanesulfinyl)sulfoniumhexafluorometallates (CH3)2SS(O)CH3+MF6- (M = As, Sb) and the spectroscopic characterization of the new thiosulfonium salts are described. Alternatively they can be obtained from methylmethanethiosulfinate by methylation. In addition the crystal structure of methanesulfinylchloride CH3S(O)Cl at 113 K is reported. The compound crystallizes in the monoclinic space group P21/n with a = 528.2(1), b = 829.2(2), c = 880.9(2) pm, β = 90.48(2)° and Z = 4.
    Notes: Die Darstellung von Dimethyl(methansulfinyl)sulfoniumhexafluorometallaten (CH3)2SS(O)CH3+MF6- (M = As, Sb) aus Methansulfinylchlorid CH3S(O)Cl und Dimethylsulfoniumhexafluorometallaten (CH3)2SH+MF6- sowie die spektroskopische Charakterisierung der neuen Thiosulfoniumsalze wird beschrieben. Alternativ können diese auch durch Methylierung von Methylmethanthiosulfinat CH3SS(O)CH3 erhalten werden. Die Ergebnisse einer Einkristallröntgenstruktur-analyse von CH3S(O)Cl bei 113 K werden mitgeteilt. Das Sulfinylchlorid kristallisiert in der monoklinen Raumgruppe P21/n mit a = 528,2(1), b = 829,2(2), c = 880,9(2) pm, β = 90,48(2)°, Z = 4.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...