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  • Wiley-Blackwell
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 887-902 
    ISSN: 0271-2091
    Keywords: potential flow ; free surface ; spectral method ; surface gravity waves ; dip formation ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper, an efficient numerical method for unsteady free surface motions, with simple geometries, has been devised. Under the potential flow assumption, the governing equation of free surface flows becomes a Laplace equation, which is treated here by means of a series expansions of the velocity potential. The free surface is represented with a height function. The present method is applied to surface gravity waves to test the stability and accuracy of the method. To show the versatility of the method, a model for a dip formation is considered. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 6 Ill.
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: ABA type block copolymers composed of poly(γ-benzyl L-glutamate) (PBLG) as the A component and poly(propylene glycol) as the B component were obtained by polymerization of γ-benzyl L-glutamate N-carboxyanhydride, initiated by amine groups at both ends of poly(propylene glycol). From circular dichroism measurements in ethylene dichloride solution as well as from infrared spectra measurements in the solid state, it was found that the polypeptide block exists in the α-helical conformation, as in PBLG homopolymer. Wide-angle X-ray diffraction patterns for the block copolymers depend on the casting solvent and show basically similar reflections as the PBLG homopolymer.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 192 (1991), S. 1041-1058 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A study of the mechanism of thermal oxidative and thermal mechanical degradation of isotactic polypropylene (PP) is reported. Size exclusion liquid chromatography has been applied to the study of molar mass distribution (MMD) of samples of PP under oxidative degradation in the presence of an incorporated organic peroxide and of samples subjected to repeated extrusion. The change in MMD of the samples of PP under controlled oxidative degradation at 230°C is explained by a random chain scission mechanism and those of the samples of PP extruded repeatedly from an extruder at 280°C can be elucidated by a mechanism of mechanical chain scission with a threshold degree of polymerization 2L, below which the chain will not undergo scission. The value of L was found to be around 500.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 1863-1872 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: ABCBA-type amphiphilic block copolymers comprising polydimethylsiloxane (PDMS), poly(ethylene oxide) (PEO), and heparin segments were synthesized by coupling reactions between end-functionalized oligomers. These multiblock copolymers were characterized to examine bulk properties using 1H-NMR, FTIR, end-group analysis, and sulfur elemental analysis. Block copolymers were further characterized in bulk using differential scanning calorimetry and X-ray diffraction measurements. The PDMS glass transition remains unchanged with increasing PEO content, indicating coexistence of pure PDMS with mixed phases. Furthermore, endothermic melting of the block copolymers shifts to higher temperatures and becomes more intense with increasing PEO molecular weight. Additionally, the crystallinity of the PEO segment in the block copolymers increases with increasing PEO molecular weight. The PEO melting endotherm peak shifts from near 318 to 323 K with annealing. In the cooling thermogram, the block copolymers exhibit two crystallization exotherms, one near 303 K and the other near 193 K, attributed to PEO and PDMS recrystallization and nucleation, respectively. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
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  • 5
    ISSN: 0730-2312
    Keywords: bronchial epithelium ; carcinogenesis ; lung cancer ; molecular cytogenetic alterations ; chemoprevention ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: Lung carcinogenesis is a multi-step process involving activation of oncogenes and inactivation of tumor suppress genes. Many molecular and cytogenetic alterations occur in the early stages of carcinogenesis. We have developed an effective culture system for human bronchial epithelial cells and lung cancer cells. Four immortalized human bronchial epithelial cell lines were established by transfecting the epithelial cells with plasmid DNA containing the early region of SV40. Some molecular and cytogenetic alterations, such as 3p-, 2q-, 9p-, c-myc translocation t(8;14) (q23; q32), were found in one immortalized bronchial epithelial cell line M when approaching malignant transformation. An increase in cell proliferation and decrease of apoptosis were noted in the late passages of the immortalized cell line M. Some molecular cytogenetic alterations were also observed in human primary non-small cell lung cancers. Molecular cytogenetic alterations during the early stage of carcinogenesis of human bronchial epithelial cells may be useful as biomarkers for both diagnosis and intermediate endpoint of chemoprevention of lung cancer. J. Cell. Biochem. Suppls. 28/29:74-80. © 1998 Wiley-Liss, Inc.
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 534-540 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of product recycle and temperature on the maximum yield of product for several different autocatalytic reactions taking place in a tubular reactor is studied.A generalized version of the maximum principle is used to determine the maximum conversion and optimal temperature profile for each of the reactions considered. The fraction of product recycled, which affects the concentration of autocatalytic agent entering the reactor, is investigated to determine its effect on the maximum conversion.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 2069-2072 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1592-1602 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The velocity contour profiles within Dean vortices produced by flowing water in a solid-walled curved tube are quantitatively measured. Magnetic resonance flow imaging using flow encoding with spin warp imaging is used in two and three dimensions to obtain these velocities. These experimental measurements are then compared with simulations obtained from solutions of the Navier-Stokes and continuity equations for three axial flow rates. Numerical solutions were obtained with a finite volume method for curved tube Poiseuille flow.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1654-1667 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of nonhlinear static and dynamic process modeling via recurrent neural networks (RNNs) is studied. An RNN model is a set of coupled nonlinear ordinary differential equations in continuous time domain with nonlinear dynamic node characteristics as well as both feedforward and feedback connections. For such networks, each physical input to a system corresponds to exactly one input to the network. The system's dynamics are captured by the internal structure of the network. The structure of RNN models may be more natural and attractive than that of feedforward neural network models, but computation time for training is longer. Our simulation results show that RNNs can learn both steady-state relationships and process dynamics of continuous and batch, single-input/single-output and multiinput/multioutput systems in a simple and direct manner. Training of RNNs shows only small degradation in the presence of noise in the training data. Thus, RNNs constitute a feasible alternative to layered feedforward back propagation neural networks in steady-state and dynamic process modeling and model-based control.
    Additional Material: 14 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 347-358 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The velocity and pressure fields and the effect of wall flux on these fields in a spiral channel are presented. As fluid flows inward through a spiral channel with constant gap and permeable walls, the streamwise flux decreases while the curvature increases. Thus, by balancing the stabilizing effect of wall suction with the destabilizing effect of increasing curvature, established vortices can be maintained along the spiral channel. This approach is used to prescribe spiral geometries with different wall fluxes. Using a weakly nonlinear stability analysis, the influence of wall flux on the characteristics of Dean vortices is obtained. The critical Dean number is reduced when suction is through the inner wall only, is slightly reduced when suction is equal through both walls, and is increased when suction is through the outer wall only. The magnitude of change is proportional to a ratio of small numbers that measures the importance of the effect of curvature. In membrane filtration applications the wall flux is typically 2 to 5 orders of magnitude less than the streamwise flow. If the radius of curvature of the channel is of the order of 100 times the channel gap, the effect on the critical Dean number is within 2% of the no-wall flux case. If the radius of curvature is sufficiently large, however, it is possible to observe effects on the critical Dean number that approach O(1) in magnitude for certain parameter ranges.
    Additional Material: 8 Ill.
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