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  • Wiley-Blackwell  (76)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2281-2292 
    ISSN: 0887-6266
    Keywords: conformation ; phonon dispersion ; α-helix ; normal modes ; poly(L-leucine) ; density of states ; heat capacity ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(L-methionine) (PMet) is one of the two sulfur containing polyamino acids. Raman, FTIR spectra, and heat capacity measurements of PMet have been well interpreted through the normal mode analysis and the density of states derived therefrom. Earlier interpretation of heat capacity data is limited because it is based on the Tarasov model, wherein the concept of group frequency and skeletal similarity are used. A special feature of some dispersion curves is their tendency to bunch in the neighborhood of the helix angle. This has been attributed to the presence of strong intramolecular interactions. Repulsion between the dispersion curves is also observed. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2281-2292, 1997
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 20 (1981), S. 373-376 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Molecular polarizabilities of glycine, L-alanine, L-proline, and polygylcine I and II have been calculated by the Lippincott delta function potential model, the atomic polarization method, and the atom-dipole interaction model. In the atom-dipole interaction model the molecular polarizabilities are dependent on atomic (or group) polarizabilities and positional coordinates of the atoms (or groups) constituting the molecule and are conformation dependent. Those obtained from the other two methods are conformation independent and dependent on bond properties only. The results are compared with those obtained from the Kerr effect and molar refraction data.
    Additional Material: 2 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 90 (1980), S. 23-36 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Schmelzkondensation wurden Ester-Ether-Copolymere hergestellt, wobei Dimethylterephthalat (DMT) und unterschiedliche Mengen von Ethylenglykol (EG) und Polyethylenglykol (PEG) (MW 400) eingesetzt wurden. Es wurden fünf Copolymerproben durch Variation des Gehalts an PEG auf der Basis von EG von 0,5 bis 2,5 mol-% hergestellt. Die Polymerproben wurden durch Bestimmung der Schmelzpunkte und Grenzviskositätszahlen charakterisiert. Die Schmelzpunkte nahmen bei Erhöhung der Polyethylenoxidsegmente im Rückgrat von 258°C auf 248°C ab. Auch die thermische Stabilität der Copolymeren verringerte sich durch Einfügen von PEG-Einheiten in das Rückgrat.Die Polymeren wurden aus der Schmelze zu Fasern versponnen. Mit der Erhöhung der Anteile von PEG in den Copolymerfasern wurde eine Erniedrigung der Reißfestigkeit und Anfangsmoduln beobachtet, während die Dehnung anstieg. Die Farbaufnahme und Wasserdampfsorption der Copolyesterfasern wurde erheblich gesteigert im Vergleich zu den Polyethylenglykolterephthalat-(PET)-Fasern.
    Notes: Ester-ether copolymers were prepared by melt condensation reaction using dimethyl terephthalate (DMT) and different quantities of ethylene glycol (EG) and poly(ethylene glycol) (PEG) (MW 400) in the initial monomer feed. Five copolymer samples were prepared by varying the contents of PEG on the basis of EG from 0.5 to 2.5 mol-%. The polymer samples were characterized by determination of melting points (mp) and intrinsic viscosities. The mp decreased from 258°C to 248°C on increasing the poly(ethylene oxide) segments in the backbone.Thermal stability of the copolymers also decreased by the introduction of PEG units in the backbone. The polymers were melt spun into fibres. With the increase of PEG in the copolymer fibres a decrease in tensile strength and initial modulus was observed while the elongation increased. The dye uptake and moisture regain of the copolyester fibres was considerably enhanced in comparison of poly(ethylene glycol terephthalate) (PET) fibres.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 26 (1957), S. 110-112 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 31 (1958), S. 219-221 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 54 (1961), S. 613-620 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Derivatives with the formulas [Na4Ca(PO3)6]n, [Na4Ba(PO3)6]n, and [Na4Zn(PO3)6]n have been prepared by heating together mixtures of NaH2PO4.2H2O, CaO (or Ba(OH)2.-8H2O or ZnO), and (NH4)2HPO4 in the molar ratios of 4:1:2 at 700 and 800°C. for 1 hr. The number-average molecular weights of these derivatives have been measured by the endgroup titration method. Their conductance has been measured in aqueous solution of varying concentration, and their properties compared with those of Graham's salt (NaPO3)n prepared under similar conditions.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 58 (1962), S. 501-516 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The complexation reaction of the polymeric metaphosphate ions has been studied with copper, calcium, barium, zinc, lead, and iron ions by physicochemical measurements indicating the formation of complex derivatives of the type (NaxM1-x/aPO3)n where a is the valency of the metal ion complexed. It has been possible to synthesize a large number of derivatives for the first time by the reactions of the following type: The progress of the reaction has been studied on a Stanton Thermogravimetric balance and the properties (composition, viscosity, molecular weight, and conductivity) of the transparent glassy complex metaphosphates have been studied in detail throwing fresh light on Graham's salt itself as well as these new derivatives.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 20 (1981), S. 9-21 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dynamics of simple polypeptides is studied both from theoretical and experimental viewpoints. Theoretically, dispersion curves and frequency distributions are obtained from Wilson's GF matrix method as modified by Higgs for an infinite helical system. The systems studied are polyglycine I and polyglycine II, polyalanine in α and α forms, poly-L-proline I and poly-L-proline II, and poly-L-hydroxyproline. Conformation sensitive modes and their dispersion in the BZ are reported. In several of these, the results are compared with the measurements from inelastic neutron scattering. Since the neutrons have a large incoherent scattering cross section for hydrogen, it enables us to examine a normal mode via the motion of protons involved. In addition, neutron scattering is not controlled by symmetry dependent “selection rules.” Conformational studies of oligomers of glycine, alanine, and proline in relation to their polymeric forms as deduced from the dispersion curves and spectroscopic studies are presented. Recent measurements on the specific heat of polyglycine and polyalanine by Finegold et al. are also reported.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 10 (1989), S. 8-15 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The reduction in fiber length during extrusion and injection molding of two commercial glass fiber-reinforced polypropylene products containing 30 percent by weight of glass fibers was studied. The first product had very small fibers of average length around 0.5 mm and also contained a coupling agent. The second product contained relatively longer glass fibers of 9 mm length and no coupling agent. In both cases, fiber attrition occurs predominantly at the solid-melt interface in the meiting zone of the extruder. However, in the short fiber granules, the maximum of the length distribution, which for the initial sample is around 0.5 mm, moved to shorter fiber lengths along the screw channels further from the hopper. In the long fiber granules, a bimodal length distribution was obtained in the intermediate channels; the first maximum was around the original length of 9 mm and the second centered around 0.5 mm. Thus, the forces at the solid-melt interface result in fiber breakage to lengths which are predominantly around 0.5 mm. The fiber attrition was observed to be more severe in injection molding apparently because of higher shear rates and also because the fibers had to pass through narrow channels. The measured distributions of fiber length along the screw channels for the two products are presented, and the possible mechanisms of fiber breakage are discussed. The mechanical properties of samples containing different fiber length distributions and the effects of fiber length and interfacial adhesion on properties are presented and discussed in Part II.
    Additional Material: 13 Ill.
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  • 10
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Two commercial grades of glass fiber-reinforced polypropylene granules, one containing short fibers of average length around 0.5 mm with a coupling agent and the other containing relatively much longer fibers mostly around 9 mm, but no coupling agent, were injection-molded into dumbbells and tested in tension between -43 and 90°C. There is considerable fiber attrition during injection molding; the fiber lengths are reduced to average values of 0.4 to 0.8 mm for thses two samples. Also during injection molding of the test sample, partial molecular alignment of the matrix (polypropylene) occurs which supplements the reinforcement of the matrix due to the aligned glass fibers (30 percent by weight) present in the composite sample. The stiffness and strength of these samples do not reflect the effects of fiber lengths since most of the fibers are of very small length in the molded specimen and also since the sample with longer fibers has a non-uniform distribution of fibers. While the interfacial shear strength does not appear to play a significant role in determining stiffness, it turns out to be extremely important in controlling strength, particularly at the higher test temperatures. The room temperature impact strength is high for the sample containing relatively longer fibers of average length around 0.8 mm in which fiber dispersion is non-uniform and fiber agglomerates are present. Acoustic emission data shows that debonding and fiber pull-out are the main contributors to sample toughness; this observation is supported by scanning electron micrographs of the fracture surfaces.
    Additional Material: 12 Ill.
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