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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 173 (1989), S. 213-218 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: An attempt was made to obtain cationic cellulose derivatives of highest possible degrees of substitution by treating dissolving grade pulps under homogeneous conditions with glycidyltrimethylammonium chloride in the solvent system dimethylacetamide/lithiumchloride. The influence of temperature, reaction time and molar ratio of the reagents was examined. A reaction time of 8 h and a temperature of 70°C have been found to be optimal. The cellulose content in solution and the molar ratio of the reagents have to be adapted to the used pulp.
    Notes: Es wurde der Versuch unternommen, durch Umsetzung von Zellstoffen mit Glycidyltrimethylammoniumchlorid im Lösungsmittelsystem Dimethylacetamid/Lithiumchlorid kationische Cellulosederivate mit möglichst hohen Substitutionsgraden zu erhalten. Hierzu wurden Temperaturabhängigkeit, Reaktionsdauer und Molverhältnis der Reaktanden untersucht. Als optimal erwies sich eine Reaktionsdauer von 8 h bei einer Reaktionstemperatur von 70°C. Der Cellulosegehalt in Lösung und das Molverhältnis der Reaktanden müssen dem verwendeten Zellstoff angepaßt werden.
    Additional Material: 3 Ill.
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  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Die als Folge einer Behandlung mit Natronlauge im Konzentrationsbereich von 0-50% NaOH eintretenden Veränderungen des Ordnungszustandes verschiedener Cellulosefasern (Holzzellstoffe und Baumwollinters) wurden infrarotspektroskopisch und röntgenographisch verfolgt. Die Bestimmung eines IR-Index als Relation der Peakflächen im Wellenzahlenbereich von 1370 und 670 cm-1 gestatteten eine mit geringem Aufwand durchzuführende Bestimmung insbesondere der im Gebiet der Natronlaugenkonzentrationen von 7.5-15%iger Lauge signifikant abfallenden Kristallinität. Weitaus aufwendigere röntgenographische Messungen des Kristallinitätsindex bestätigen die infrarotspektroskopisch erhaltenenen Befunde. Es ergibt sich die Möglichkeit, anhand gewisser Unterschiede im Verlauf der IR-Indexkurven Schlüsse in bezug auf die Aktivierungsfähigkeit einzelner Faserproben zu ziehen.
    Additional Material: 7 Ill.
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  • 3
    ISSN: 0192-253X
    Keywords: gonad differentiation ; gene expression ; two-dimensional micro gel electrophoresis ; Life and Medical Sciences ; Genetics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: Gonadal protein patterns were studied during development in the rat by two-dimensional micro-gel electrophoresis. Specific proteins were detected in both the male and the female sex at the morphologically indifferent state (two female- and one male-specific) and during differentiation. At the onset of gonadal differentiation (day 14) two additional sex-specific proteins were discovered in the male and two in the female. These proteins remained expressed during further development. One testicular protein was restricted to the cytosol of the tunica albuginea. The other one was absent from the tunica. In the female gonad, the two proteins were membrane-specific, one present in germ cells, the other in somatic cells. In the testis, one additional protein was discovered at postnatal day 1. Thus according to biochemical criteria there is no indifferent state of gonadal development. The testis and ovary express sex-specific genes both before and after the onset of gonadal differentiation.
    Additional Material: 8 Ill.
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  • 4
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Primäre Sulfochloride liefern mit 1.1-Dimorpholino-äthen und -propen-(1) in Gegenwart von Triäthylamin bei Raumtemperatur teils durch β-Acylierung 1.1-Dimorpholino-2-alkylsulfon-alkene (V), die zu 2-Alkylsulfon-alkansäure-morpholiden (VI) hydrolysierbar sind, teils 3-Morpholino-thieten-1.1-dioxyde (III + IV). Die Bildung der ungesättigten Vierringsulfone wird als Cycloaddition des Keten-N.N-acetals an in situ gebildetes Sulfen (RCH=SO2) mit anschließender Morpholin-Eliminierung gedeutet.
    Additional Material: 1 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 66 (1994), S. 1178-1178 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 608-612 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 2 (1951), S. 51-54 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Wirtschaftliche Bedeutung der Holzschutzbehandlung  -  Aufgaben und Einsatzgebiete des baulichen und chemischen Holzschutzes  -  Überblick über die Arbeiten der Deutschen Gesellschaft für Holzschutz und des Prüfausschusses für Holzschutzmittel  -  Notwendigkeit verstärkter Aufklärungsarbeit  -  Durchführung der baulichen und chemischen Holzschutzmaßnahmen  -  aktuelle Holzschutzprobleme.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester, West Sussex : Wiley-Blackwell
    Mathematical Methods in the Applied Sciences 5 (1983), S. 195-215 
    ISSN: 0170-4214
    Keywords: Mathematics and Statistics ; Applied Mathematics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics
    Notes: As is well known the real Heisenberg nilpotent group A(R) constitutes the group-theoretic embodiment of the Heisenberg canonical commutation relations (CCR) of classical quantum mechanics. In this connection, quantum mechanics stands for the quantum-mechanical description, at a given instant of time, of a non-relativistic microparticle moving in the one-dimensional configuration space R and having the plane R2 as its (flat) phase space. In fact, the (nilpotent) Lie algebra n of Ã(R) reflects the Weyl equations which are global versions of the Heisenberg CCR. Unfortunately, the subject of Heisenberg nilpotent groups is outside quantum mechanics and all the more outside mathematical physics not as commonly known as it should be considering its wide range of applications in a variety of different fields. The present paper which has two parts aims to develop a central topic of nilpotent harmonic analysis, to wit, the microparticle model, the lattice model which will be realized on the Heisenberg compact nilmanifold, and the complex wave model (or Bargmann-Fock-Segal model) of the linear Schrödinger representation of Ã(R) in order to examine geometrically several applications which are governed by the real Heisenberg nilpotent group Ã(R). These applications are in Part I the classical Whittaker-Shannon sampling theorem which is of basic importance in signal processing, to wit, for the transmission of digital signals as well as analog signals, and in Part II the Subbotin-Schoenberg existence and uniqueness theorem of cardinal spline interpolation. Moreover, Part II indicates briefly some connections of the aforementioned models to the Wigner phase-space quasiprobability density function of quantum statistical mechanics via the Schwartz kernels theory on unimodular Lie groups, an approach to the cross- and autoambiguity functions of radar synthesis, and to the Zak transform of solid state physics. The second part also points out some relations of harmonic analysis of the finite nilpotent group A(Z/NZ) to periodic spline interpolants admitting N equidistant knots on the one-dimensional compact torus group T. These last examples should serve mainly as hints for some further lines of investigations in the field of applications of nilpotent harmonic analysis.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 90 (1957), S. 1337-1342 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während aromatische Quecksilberverbindungen mit Bleitetraacetat in Arylbleitriacetate übergeführt werden, zerfallen die entsprechenden aliphatischen Bleiverbindungen nach einem ionischen Mechanismus in Blei(II)-acetat und Alkylacetat. Bei diesen Umsetzungen reagiert das Pb(OAc)3⊕-Kation als elektrophiles Reagens.
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  • 10
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus primären Sulfochloriden und tertiären Enaminen entstehen in Gegenwart von Triäthylamin thermisch bis gegen 200° stabile β-Dialkylamino-trimethylensulfone (V). Für diese Synthese eignen sich stark basische Enamine mit oder ohne β-H-Atom. Sekundäre Sulfochloride bilden keine Trimethylensulfone.  -  Die Synthese der sehr schwach basischen Vierring-Sulfone wird als Cycloaddition des Enamins an in situ gebildetes Sulfen (RCH = SO2) gedeutet.
    Additional Material: 1 Tab.
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