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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 37 (1986), S. 451-456 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zuverlässigkeit elektrochemischer Methoden bei der Untersuchung von Prothesen aus nichtrostendem Stahl mit AluminiumoxidüberzugIm vorliegenden Bericht wird die Korrosionsbeständigkeit von Prothesen aus nichtrostendem Stahl mit Aluminiumoxidüberzug erörtert; als Versuchsmaterial dienten Stahl AISI 316 L mit plasmagespritztem Aluminiumoxidüberzug (mit und ohne Nickel als Zwischenschicht).Die Nickelschicht soll die Haftung zwischen dem keramischen Material und dem Stahl gewährleisten. Als Prüfmedium diente die Hank'sche Lösung, da diese Ähnlichkeit mit organischen Flüssigkeiten aufweist. Zur Verbesserung der Aussagefähigkeit der Ergebnisse wird empfohlen, mehrere der nachstehenden elektrochemischen Methoden nebeneinander zu verwenden: Bestimmung der Zeitabhängigkeit des Korrosionspotentials; Polarisationswiderstandsmessung; coulostatische Methoden und Wechselstrommethoden. Bei der elektrochemischen Untersuchung von keramikbeschichtetem nichtrostendem Stahl im passiven Zustand ergeben sich einige spezifische Schwierigkeiten durch die Störung der Arbeitselektrode infolge der einwirkenden elektrischen Signale, wodurch die Genauigkeit der Korrosionsgeschwindigkeitsmessung beeinträchtigt wird. Diese Schwierigkeiten treten nicht auf, wenn eine Kombination mit einer aktiveren Zwischenschicht benutzt wird.
    Notes: The corrosion resistance of alumina-covered stainless steel prosthesis is discussed in this report. The test material was an AISI 316L steel with a plasma sprayed on alumina coating, applied directly or through an intermediate nickel base layer, whose mission is to guarantee a perfect adherence between the ceramic material and the steel. Use was made in the laboratory of Hank's solution as test medium since this solution is similar to organic fluids. In order to increase the reliability of the results the simultaneous use of various of the following electrochemical methods are recommended: Determination of corrosion potential with the time, polarization resistance method, coulostatic method and a.c. methods. The use of electrochemical methods to study ceramic-covered stainless steel in the passive state poses some specific difficulties accruing from the disturbance of the working electrode by the applied electrical signals which limit the accuracy of the corrosion rate measurements. These difficulties do not appear in the case of a material having a intermediate layer which is more active.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 40 (1989), S. 668-673 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Umweltfaktoren als Ursache der ungewöhnlichen Korrosion von verzinktem StahlEine ungewöhnlich starke Korrosion von feuerverzinktem Stahl in einer subtropischen Meeresatmosphäre wurde untersucht. Aufgrund der mittels Röntgenbeugungsanalyse der Korrosionsprodukte, des umgebenden Bodens und des aus der Luft abgelagerten Staubs sowie aufgrund der REM-Befunde und der EDAX-Analyse der losen Deckschicht sowie aufgrund der metallographischen Untersuchung von Schnitten durch verzinkten Stahl mit unterschiedlichem Korrosionsgrad wird ein Mechanismus für den Angriff vorgeschlagen, der die außerordentlich hohe Korrosionsgeschwindigkeit des verzinkten Stahls auf die dort herrschenden speziellen atmosphärischen Verhältnisse zurückführt.
    Notes: A phenomenon of unusual heavy corrosion of hot dip galvanized structural steelwork in a subtropical severe marine atmosphere has been studied. Through the data optained from X-ray diffraction analysis of corrosion products, surrounding soil samples and environmental dust samples, and from SEM observations and EDAX analysis of loose corrosion scale, as well as from the information provided by the metallographic study of galvanized steel sections with different degree of corrosion, a mechanism of attack has been proposed, which accounts for the special environmental factors prevailing on the place.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 39 (1988), S. 364-369 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Repassivierungsfähigkeit von keramikbeschichteten EdelstahlprothesenDas Durchbruchs- und das Repassivierungspotential von keramikbeschichteten Prothesen aus nicht rostendem Stahl sind in Hanks-Lösung und an Implantaten an Hunden bestimmt worden. Diese Werkstoffe zeigen geringe Lochkorrosionsempfindlichkeit und starke Repassivierungsfähigkeit. Der Einfluß von Oberflächenrauhigkeit, Tauchzeit und der Homogenisierungsbehandlung auf das Lochfraßverhalten wird diskutiert.
    Notes: The breakdown and repassivation potentials of stainless steel-ceramic prostheses have been determined both in a Hanks' solution and in implants in dogs. These materials show low susceptibility to pitting corrosion as well as a high repassivation capability. The influence of surface roughness, exposure time and homogenization treatment on the pitting corrosion behaviour is studied.
    Additional Material: 8 Ill.
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  • 4
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 33S NMR spectra have been obtained in the FT mode for some sulphones and sulphonic acids. The investigated compounds show narrow resonance lines. In the case of sulphones, the range of 33S chemical shifts is sufficiently wide, i.e. the effects due to changes in substituents are significant enough to allow further use of the 33S NMR of sulphones for quantitative analysis in petroleum chemistry.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 31 (1996), S. 313-317 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: In this work the corrosion behavior of a new biomaterial, the MA-956 superalloy, immersed in Hank's solution is evaluated. A comparison with conventional metallic alloys used as articular implants is established. To determine the corrosion behavior we employed electrochemical methods: evaluation of corrosion potential Ecorr, electrochemical impedance spectroscopy (EIS), and anodic polarization curves. The corrosion resistance of the MA-956 superalloy preoxidized at 1100°C during 100 h is at least two orders of magnitude higher than for the other alloys. This satisfactory behavior is stationary with time. Also the probability of the appearance of the pitting corrosion process is very low. When cracking is generated in the α-alumina layer the repassivation process is assured because of the high Cr content in the superalloy. This study is the first step in proposing this new alloy as a biomaterial. The low toxicity of these metallic alloys in the physiological environment suggests that in vivo their biocompatibility could be satisfactory. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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