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  • Wiley-Blackwell  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 11 (1990), S. 24-31 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Glass-fiber-reinforced polystyrene (GFPS1) and polyethersulfone (GFPES) injection-moldings containing 20 wt% glass have been weathered in Jeddah, Saudi Arabia, for up to one year. The retained strength and ductility were, generally, better than in the corresponding unreinforced polymers. The tensile strength fell to ca 73% of the initial, unexposed value, (GFPS1) and ca 77% (GFPES), whereas the extension to break values fell to ca 50% and 76%, respectively, after one year of weathering. The inclusion of carbon black in reinforced polystyrene (GFPS(B)) resulted in a barely perceptible drop in strength (to ca 98%) and a greatly improved reduction in extension to break, dropping only to ca 81% after one year. Residual stress levels were measured and were found to be insufficient to have a significant influence on fracture behavior. In GFPES they were generally less than 2MN/m2 except at a location ≃0.3 mm from the surface, where compressive stresses of up to 4 MN/m2 were present. No significant change in residual stress occurred with exposure in GFPES. With GFPS1 the stress levels were insignificant ( 〈1 MN/m2) through most of the bar both before and after exposure. With unexposed GFPS(B) the stresses were 〈1 MN/m2 except within 0.2 mm of the surface, where they rose steeply, though probably not above 5 MN/m2. After weathering the stresses were everywhere 〈1 MN/m2, but the sense of the residual stresses had reversed near to the exposed surface. This is attributed to radiant heating, and is undesirable because it may lead to distortion.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 2033-2051 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Birefringence measurements have been made on six glassy polymers during stress-relaxation and recovery experiments at temperatures below Tg. Of the six polymers tested only one pair, poly(ethylene terephthalate) and a glassy polyamide (“Trogamid”), show a strong mutual resemblance in the behavior of birefringence under these conditions. The results are discussed with reference to molecular structure, and, although detailed interpretations are not offered, it is observed that the behavior is less complex for polymers which possess their most polarizable groups in the main chain or attached rigidly to it than for those polymers having polarizable side groups with relaxations which do not involve the main chain. All six polymers have been tested in injection-molded form, and the possible consequences of this are considered. The major differences observed to occur between the different materials do not appear to be related to processing, however, and some results obtained using specimens prepared in other ways are also presented to illustrate this.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 129-144 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polycarbonate injection moldings have been conditioned for various times in (i) hot water (40, 60, 80, and 100°C) or (ii) in a temperature gradient (with hot surface/cold surface temperatures 80/25, 100/25, 120/35, and 140/60°C). Water absorption occurred in hot water and caused the formation of disc-shaped flaws, which were located at all depths within the bars and at all orientations. The presence of the flaws caused severe embrittlement and cracks were nucleated by them during uniaxial tensile testing. Residual stress levels were found to be diminished by hot water conditioning more than those in bars conditioned at the same temperatures in air. The sense of the residual stresses reversed in a bar that was allowed to cool slowly in the water bath, an observation attributed to desorption. It was generally found that the flaws near the surface healed on allowing the bars to stand in air at room temperature. Temperature gradient conditioning caused reversal of the sense of the residual stresses near to the hot surface at the two higher temperatures used and significant reduction in magnitude at the lower temperatures. Fracture nucleated at this surface during uniaxial tensile testing.
    Additional Material: 23 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 83-93 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The isothermal crystallization of isotactic polypropylene at different temperatures in the presence of fibrous substrates has been investigated. It is shown that preferential transcrystalline growth occurs at the fiber surface and that changes in nucleation density in the bulk material adjacent to the fibers also occur, the extent of which is dependent on temperature and fiber volume fraction. The effects are discussed in terms of the diffusion of heterogeneities in the bulk due to interaction and the adsorption on the fibers.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 21 (1983), S. 31-37 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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