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  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental study of the effect of crystallinity on the light scattering of regenerated cellulose tubular films is reported. Several films were prepared by varying manufacturing conditions, so that thickness and surface roughness were maintained approximately constant and the degrees of crystallinity varied between 38 and 66%. The scattered radiation intensity, measured between 220 and 550 nm decreases with the increasing wavelength. It was demonstrated that for the polymeric films studied, there was excellent agreement between crystallinity and scattering radiation intensity for a given wavelength. It was found that for crystallinity values less than around 57%, scattered radiation intensity decreases with increasing crystallinity, the reverse of that for crystallinity values greater than that percentage.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 13 (1981), S. 97-107 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stoichiometric and, in most cases, absolute rates of coupling of a series of m- and p-substituted benzenediazonium ions with 2,3-dihydroxynaphthalene-6-sulfonate ion (1) have been determined (i) at pH 5.6 (when one OH group is partly monoionized) and (ii) at pH 9.9 (when one OH group is completely ionized and the second slightly so). The rates at both pH values correlate with the σ+ parameter (except for the most reactive ArN2+ at pH 9.9) and the contributions of the two reactive forms of the coupler evaluated. Detailed pH dependences of the coupling rate of the p-chlorobenzenediazonium ion with (1) reveal a strong interaction between (1) and the borate ion, which strongly influences the coupling rate. Coupling rates have also been measured for both diazonium ions and couplers of importance in the diazo reprographic process.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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