ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The deformation density and potential have been determined in molecular crystals of tricyclo[4.4.1.01,6]ndeca-2,4,7,9-tetraene-11,11-dicarbonitrile at 150 K from X-ray diffraction measurements. A significant degformation density peak is found near the mid-poind of the the transannular bond. The four short bonds in the annuelene ring acquire slightly more residual density compared to the other bonds, confirming the bisnorcaradienic character of the molecule. Similar trends are noted in the deformation electrostatic potential maps.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19840670707
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