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Disproportionation reactions between CF2H and C2H5 radicals in the gas phase (1982)

Nilsson, William B. ; Pritchard, Glyn O.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 14 (1982), S. 299-323

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The disproportionation and combination reactions between CF2H and C2H5 radicals have been studied in the gas phase from room temperature to 70°C. For the pathway which yields CF2H2 + C2H4, relative to CF2HC2H5, Δ = 0.072 ± 0.019. The competing reaction channel that produces CF2 + C2H6 is approximately four times as efficient, with Δ = 0.265 ± 0.038. With CF2D radicals an isotope effect for the CF2 + C2H5D reaction pathway was observed with Δ ≅ 0.2.

Additional Material: 7 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550140310

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