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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 2365-2371 
    ISSN: 0887-6266
    Keywords: positron annihilation ; positronium ; free volume ; hole ; gas permeation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Free-volume hole sizes, fractions, and distributions in a series of polycarbonate-based polymers are measured by using positron annihilation lifetime (PAL) spectroscopy. Correlations between the obtained free-volume hole properties and gas diffusion coefficients are observed. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 47 (1996), S. 290-302 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The bromo-substituted main chain liquid crystal polyesters poly(3-bromo-4-oxybiphenylene-4′-carbonyl) (PBOBC) and poly(5-bromo-6-oxy-2-naphthoyl) (PBONY) have been polymerized as lamellar single crystals using the confined thin film melt polymerization (CTFMP) technique. Electron diffraction indicates a triclinic (pseudo-orthorhombic) unit cell with a=12.71, b=3.85, c=10.50 Å, α=β=γ=90° for PBOBC and a monoclinic unit cell with a=13.02, b=4.06, c=17.15 Å, β=101° for PBONY. The crystal structures of the two polymers have been simulated by the Cerius2 program and are suggested to have space group P for PBOBC and space group P121/c1 for PBONY. DSC measurements indicate that these two bromo-substituted fully aromatic polyesters have crystal-mesophase transition temperatures (Tk-m=389°C for PBOBC and 429°C for PBONY) with TGA indicating the onset of degradation at similar temperatures (400 and 420°C). The Tk-m are between those of the corresponding non-substituted and phenyl-substituted aromatic polyesters. Possible reasons for the Tk-m differences are considered in detail.
    Additional Material: 14 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 18 (1994), S. 1083-1105 
    ISSN: 0271-2091
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Solution methods are presented for the large systems of linear equations resulting from the implicit, coupled solution of the Navier-Stokes equations in three dimensions. Two classes of methods for such solution have been studied: direct and iterative methods.For direct methods, sparse matrix algorithms have been investigated and a Gauss elimination, optimized for vector-parallel processing, has been developed. Sparse matrix results indicate that reordering algorithms deteriorate for rectangular, i.e. M × M × N, grids in three dimensions as N gets larger than M. A new local nested dissection reordering scheme that does not suffer from these difficulties, at least in two dimensions, is presented. The vector-parallel Gauss elimination is very efficient for processing on today's supercomputers, achieving execution rates exceeding 2.3 Gflops the Cray YMP-8 and 9.2 Gflops on the NEC on SX3.For iterative methods, two approaches are developed. First, conjugate-gradient-like methods are studied and good results are achieved with a preconditioned conjugate gradient squared algorithm. Convergence of such a method being sensitive to the preconditioning, a hybrid viscosity method is adopted whereby the preconditioner has an artificial viscosity that is gradually lowered, but frozen at a level higher than the dissipation introduced in the physical equations. The second approach is a domain decomposition one in which overlapping domain and side-by-side methods are tested. For the latter, a Lagrange multiplier technique achieves reasonable rates of convergence.
    Additional Material: 15 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 1815-1818 
    ISSN: 0887-624X
    Keywords: 1,3-pentadiene ; cationic polymerization ; crosslinking ; chain transfer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 3575-3583 
    ISSN: 0887-624X
    Keywords: latexes ; dispersion polymerization ; styrene ; PEO macromonomer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The particle sizes and their size distributions of latexes from the dispersion polymerization of styrene using a small amount of ω-methoxy poly(ethylene oxide)n undecyl-α-methacrylate macromonomer (PEO-R-MA-40) as a polymerizable stabilizer in ethanol-water media have been studied. Monodisperse or/and nearly monodisperse latex particles from 0.1 to 1 μm in diameter were readily obtained. The diameter of latex particles follows the relationship Dvad ∝ θ0.33 [PEO-R-MA-40]-0.60 [styrene]01.02 [AIBN]o-0.09, where θ is the fractional conversion of styrene. Except for the styrene concentration dependency, this relationship is in excellent agreement with the model developed by Paine11 and modified by Kawaguchi et al.13 When the surface composition of the grafted PEO macromonomer on the latex particles exceeded 16% as analyzed by X-ray photoelectron spectroscopy (XPS), the particles were nearly monodisperse. In terms of polymerization, this occurred around 18% conversion of styrene. Beyond this critical state of polymerization, the latex particles grew bigger with more PEO macromonomer-styrene copolymers situated on the particle surface. The effect of various factors on the particle size distribution is also discussed. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3575-3583, 1997
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2087-2090 
    ISSN: 0887-624X
    Keywords: 1,3-pentadiene ; Cationic Polymerization ; crosslinking ; chain transfer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 296-303 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 17 Ill.
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  • 8
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Instrumental parameters and possible correction procedures for hydrogen-transfer phenomena are studied, with emphasis on the improvement of quantitative measurements in selected ion monitoring mass spectrometry. The intensity ratio of the m/z 387 and 386 ions, derived from cholesterol, are measured by an HP-5995 mass spectrometer using different parameters, including calibration peak width, mass filter window size and ion monitoring dwell time. The intrinsic ratio of these two ions is calculated with a correction procedure accounting for the [M—H]+ and [M—2H]+ hydrogen-transfer phenomena.
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 12 (1985), S. 638-642 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A direct mass spectrometric measurement method is developed for the determination of 13C enrichment and chemical purity of a labelled compound. The labelled compound is mixed with various amounts of unlabelled analogue to provide a series of mixtures containing different but comparable quantities of labelled and unlabelled species. Intensity ratios of selected isotopically anologous ions from these two species are determined using selected ion monitoring. Equations are established to relate measured intensity ratios to sample mixture weight ratios, chemical purities of the labelled and unlabelled compounds, ion composition and isotopic abundance of the enriched and unenriched carbons, A non-linear regression procedure, based on the measured intensity ratio, the mixture weight ratio and the known chemical purity of the unlabelled compound, is used to resolve the chemical purity and the isotopic abundance yielding results with standard errors of 1.0 and 0.4%, respectively. This procedure is suitable for compounds labelled with more than 60% of an isotope.
    Additional Material: 3 Ill.
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  • 10
    ISSN: 1059-910X
    Keywords: Single-crystal sapphire ; Oxygen-annealing ; RHEED ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Natural Sciences in General
    Notes: Annealed (0001) surfaces of single-crystal sapphire (α-Al2O3) rod have been studied in the electron microscope using reflection electron microscopy (REM), scanning reflection electron microscopy (SREM), and reflection high energy electron diffraction (RHEED). Annealed surfaces of (0001) sapphire are vicinal and characterized by close-packed (0001)-oriented terraces separated by faceted multiple-height steps, with edges parallel to energetically preferred low-index directions (〈101―0〉 and 〈112―0〉). These structural features are not seen on cleaved surfaces or polished surfaces treated at temperatures 〈 1,250°C. Oxygen-annealing produces clean surfaces which prove useful for investigating the interaction of deposited metals with the (0001) sapphire. Both REM and SREM (with microdiffraction spots) techniques have been used to observe fine structure of flat Ag islands on the scale of 1 - 100 nm on the (0001)-oriented terraces as well as aggregations at the steps. A preliminary result on interaction with Cu is also included.
    Additional Material: 11 Ill.
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