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  • Wiley-Blackwell  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemistry - A European Journal 1 (1995), S. 430-435 
    ISSN: 0947-6539
    Keywords: amino acids ; asymmetric synthesis ; BNCT ; carboranes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two α-amino acids containing the 1,2-dicarba-closo-dodecaborane (12) cage, namely, 5-(1,2-dicarba-closo-dodecaboran (12)-1-yl)-2-aminopentanoic acid (1) and 5-(2-methyl-1,2-dicarba-closo-dodecaboran (12)-1-yl)-2-aminopentanoic acid (2), were prepared by asymmetric synthesis (e.p. 〉 98%) by using the chiral glycine equivalent, imidazolidinone 3, introduced by Seebach, and Oppolzer's camphor-derived sultam derivative 4. The dextrorotatory enantiomers (sodium D line in methanol) of the amino acids 1 and 2 were both shown to have (S) configuration.
    Type of Medium: Electronic Resource
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