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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 663-677 
    ISSN: 0271-2091
    Keywords: CFD ; control volume ; polar cylindrical grid ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the numerical simulation of fluid flows using a polar cylindrical grid, grid lines meet at a single point on the axis of the polar cylindrical grid system; this makes the grids around the axis degenerate from being general quadrilaterals into triangles. Therefore, a special treatment must be performed when the axis has to be included in the computational domain in order to solve a non-axisymmetrical fluid flow problem. In this paper a new numerical method has been developed to deal with the difficulty of the axis when the control volume technique is used with a non-staggered grid arrangement. Two illustrative examples of the proposed method are presented for simulating the fluid flows on the axis and all the numerical results obtained for the two examples are shown to be in good agreement with the available analytical solutions. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2339-2345 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The state of p-phenylphenol molecules in dioxane/water mixture, a commonly used reaction system for enzymatic polymerization of phenols and aromatic amines, was investigated by difference UV absorption spectroscopy and Fourier transform (FT) Raman spectroscopy. The aggregate of p-phenylphenols is found on the basis of the exciton peaks observed in difference UV absorption spectra. FT Raman spectroscopy demonstrates further that p-phenylphenol molecules aggregate together in “face to face” fashion. A simplified model is proposed for aggregation of p-phenylphenol molecules in dioxane/water mixture, which can elucidate the variation of the molecular weight of poly (p-phenylphenol) coupled in the reaction system. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 30 (1992), S. 1247-1254 
    ISSN: 0749-1581
    Keywords: Cembrene ; Carbon-carbon coupling ; INADEQUATE ; Selective pulses ; Shaped pulses ; Sequential excitation ; Improved data accumulation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A 1D pulse sequence designed for the selective detection of carbon-carbon connectivities and the measurement of the corresponding coupling constants is presented. The sequence takes advantage of the increased sensitivity and the higher accuracy obtained with multiselective excitation and 1D detection, respectively. The sequence is shown to be a valuable alternative to the popular 2D INADEQUATE experiment in cases where parts, instead of the full, carbon-carbon connectivity matrix are of interest. The sequence is especially useful for the selective measurement of the stereochemically interesting long-range coupling constants.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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